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N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide

In the crystal structure of the title compound, C(22)H(28)N(2)O(6)S(2), the asymmetric unit contains one half mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C= O and C—H bonds in the central amide and aliphatic segments are anti to the...

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Autores principales: Rodrigues, Vinola Z., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213597/
https://www.ncbi.nlm.nih.gov/pubmed/22091174
http://dx.doi.org/10.1107/S1600536811029783
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author Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_facet Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
author_sort Rodrigues, Vinola Z.
collection PubMed
description In the crystal structure of the title compound, C(22)H(28)N(2)O(6)S(2), the asymmetric unit contains one half mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C= O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The mol­ecule is bent at the S atom with an C—SO(2)—NH—C(O) torsion angle of −76.4 (3)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O) segment in the two halves of the mol­ecule is 67.2 (1)°. In the crystal, N—H⋯O(C) inter­molecular hydrogen bonds link the mol­ecules into chains along the b axis.
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spelling pubmed-32135972011-11-16 N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide Rodrigues, Vinola Z. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(22)H(28)N(2)O(6)S(2), the asymmetric unit contains one half mol­ecule with a center of symmetry at the mid-point of the central C—C bond. The conformations of all the N—H, C= O and C—H bonds in the central amide and aliphatic segments are anti to their adjacent bonds. The mol­ecule is bent at the S atom with an C—SO(2)—NH—C(O) torsion angle of −76.4 (3)°. The dihedral angle between the benzene ring and the SO(2)—NH—C(O) segment in the two halves of the mol­ecule is 67.2 (1)°. In the crystal, N—H⋯O(C) inter­molecular hydrogen bonds link the mol­ecules into chains along the b axis. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213597/ /pubmed/22091174 http://dx.doi.org/10.1107/S1600536811029783 Text en © Rodrigues et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rodrigues, Vinola Z.
Foro, Sabine
Gowda, B. Thimme
N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title_full N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title_fullStr N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title_full_unstemmed N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title_short N,N′-Bis(4-methyl­phenyl­sulfon­yl)­suberamide
title_sort n,n′-bis(4-methyl­phenyl­sulfon­yl)­suberamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213597/
https://www.ncbi.nlm.nih.gov/pubmed/22091174
http://dx.doi.org/10.1107/S1600536811029783
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