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1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene
The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diarylethene derivative with 9-ethylcarbazol-3-yl substituents. The molecule adopts a photoactive antiparallel conformation [Irie (2000). Chem. Rev. 100, 1685–1716; Kobatake et al. (2002). Chem. Commun. pp. 2804–2805],...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213625/ https://www.ncbi.nlm.nih.gov/pubmed/22091202 http://dx.doi.org/10.1107/S1600536811029539 |
Sumario: | The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diarylethene derivative with 9-ethylcarbazol-3-yl substituents. The molecule adopts a photoactive antiparallel conformation [Irie (2000). Chem. Rev. 100, 1685–1716; Kobatake et al. (2002). Chem. Commun. pp. 2804–2805], with a dihedral angle between the mean planes of the two thiophene rings of 56.23 (6)°. The distance between the two reactive C atoms is 3.497 (3) Å. In the crystal, two molecules are associated through a pair of C—H⋯F intermolecular hydrogen bonds, forming a centrosymmetric dimer. Dimers are linked by weak π–π interactions [centroid–centroid distance = 3.8872 (13) Å], forming chains along the c axis. |
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