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1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene
The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diarylethene derivative with 9-ethylcarbazol-3-yl substituents. The molecule adopts a photoactive antiparallel conformation [Irie (2000). Chem. Rev. 100, 1685–1716; Kobatake et al. (2002). Chem. Commun. pp. 2804–2805],...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213625/ https://www.ncbi.nlm.nih.gov/pubmed/22091202 http://dx.doi.org/10.1107/S1600536811029539 |
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author | Kubono, Koji Synmyouzu, Teruo Goto, Kenta Tsujioka, Tsuyoshi Tani, Keita |
author_facet | Kubono, Koji Synmyouzu, Teruo Goto, Kenta Tsujioka, Tsuyoshi Tani, Keita |
author_sort | Kubono, Koji |
collection | PubMed |
description | The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diarylethene derivative with 9-ethylcarbazol-3-yl substituents. The molecule adopts a photoactive antiparallel conformation [Irie (2000). Chem. Rev. 100, 1685–1716; Kobatake et al. (2002). Chem. Commun. pp. 2804–2805], with a dihedral angle between the mean planes of the two thiophene rings of 56.23 (6)°. The distance between the two reactive C atoms is 3.497 (3) Å. In the crystal, two molecules are associated through a pair of C—H⋯F intermolecular hydrogen bonds, forming a centrosymmetric dimer. Dimers are linked by weak π–π interactions [centroid–centroid distance = 3.8872 (13) Å], forming chains along the c axis. |
format | Online Article Text |
id | pubmed-3213625 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32136252011-11-16 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene Kubono, Koji Synmyouzu, Teruo Goto, Kenta Tsujioka, Tsuyoshi Tani, Keita Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diarylethene derivative with 9-ethylcarbazol-3-yl substituents. The molecule adopts a photoactive antiparallel conformation [Irie (2000). Chem. Rev. 100, 1685–1716; Kobatake et al. (2002). Chem. Commun. pp. 2804–2805], with a dihedral angle between the mean planes of the two thiophene rings of 56.23 (6)°. The distance between the two reactive C atoms is 3.497 (3) Å. In the crystal, two molecules are associated through a pair of C—H⋯F intermolecular hydrogen bonds, forming a centrosymmetric dimer. Dimers are linked by weak π–π interactions [centroid–centroid distance = 3.8872 (13) Å], forming chains along the c axis. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213625/ /pubmed/22091202 http://dx.doi.org/10.1107/S1600536811029539 Text en © Kubono et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kubono, Koji Synmyouzu, Teruo Goto, Kenta Tsujioka, Tsuyoshi Tani, Keita 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title | 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title_full | 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title_fullStr | 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title_full_unstemmed | 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title_short | 1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
title_sort | 1,2-bis[5-(9-ethyl-9h-carbazol-3-yl)-2-methylthiophen-3-yl]-3,3,4,4,5,5-hexafluorocyclopentene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213625/ https://www.ncbi.nlm.nih.gov/pubmed/22091202 http://dx.doi.org/10.1107/S1600536811029539 |
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