N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate

In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol­ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond and the NH...

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Detalles Bibliográficos
Autores principales: Liu, Wei-Hua, Song, Shuang-Ju, Ma, Jing-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213628/
https://www.ncbi.nlm.nih.gov/pubmed/22091205
http://dx.doi.org/10.1107/S1600536811030108
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author Liu, Wei-Hua
Song, Shuang-Ju
Ma, Jing-Jun
author_facet Liu, Wei-Hua
Song, Shuang-Ju
Ma, Jing-Jun
author_sort Liu, Wei-Hua
collection PubMed
description In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol­ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol­ecule. In the crystal, inter­molecular O—H⋯O hydrogen bonds involving the methanol solvent mol­ecule link the benzohydrazide mol­ecules to form chains which propagate along the a axis.
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spelling pubmed-32136282011-11-16 N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate Liu, Wei-Hua Song, Shuang-Ju Ma, Jing-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)BrN(3)O(4)·CH(4)O, the benzohydrazide mol­ecule is nearly planar [maximum deviation = 0.110 (2) Å]. The mean planes of the two benzene rings make a dihedral angle of 8.4 (3)°. In the benzohydrazide mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond and the NH group is hydrogen bonded to the methanol solvent mol­ecule. In the crystal, inter­molecular O—H⋯O hydrogen bonds involving the methanol solvent mol­ecule link the benzohydrazide mol­ecules to form chains which propagate along the a axis. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213628/ /pubmed/22091205 http://dx.doi.org/10.1107/S1600536811030108 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Wei-Hua
Song, Shuang-Ju
Ma, Jing-Jun
N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_full N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_fullStr N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_full_unstemmed N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_short N′-(5-Bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
title_sort n′-(5-bromo-2-hy­droxy­benzyl­idene)-4-nitro­benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213628/
https://www.ncbi.nlm.nih.gov/pubmed/22091205
http://dx.doi.org/10.1107/S1600536811030108
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AT majingjun n5bromo2hydroxybenzylidene4nitrobenzohydrazidemethanolmonosolvate

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