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N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide

The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent mol­ecules in each of which the P atom adopts a distorted tetra­hedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phosph...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Saneei, Anahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213631/
https://www.ncbi.nlm.nih.gov/pubmed/22091208
http://dx.doi.org/10.1107/S1600536811030194
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent mol­ecules in each of which the P atom adopts a distorted tetra­hedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phospho­ramide mol­ecules are disordered over two sets of sites, with site occupancies of 0.766 (7) and 0.234 (7) for one ring and 0.639 (10) and 0.361 (10) for the other. In the second phospho­ramide mol­ecule, one of the NC(4)H(8)O moieties is disordered over two sets of sites with site occupancies of 0.807 (6) and 0.193 (6). In the crystal, pairs of inter­molecular N—H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers.