Cargando…
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide
The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent molecules in each of which the P atom adopts a distorted tetrahedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phosph...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213631/ https://www.ncbi.nlm.nih.gov/pubmed/22091208 http://dx.doi.org/10.1107/S1600536811030194 |
_version_ | 1782216167104970752 |
---|---|
author | Pourayoubi, Mehrdad Saneei, Anahid |
author_facet | Pourayoubi, Mehrdad Saneei, Anahid |
author_sort | Pourayoubi, Mehrdad |
collection | PubMed |
description | The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent molecules in each of which the P atom adopts a distorted tetrahedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phosphoramide molecules are disordered over two sets of sites, with site occupancies of 0.766 (7) and 0.234 (7) for one ring and 0.639 (10) and 0.361 (10) for the other. In the second phosphoramide molecule, one of the NC(4)H(8)O moieties is disordered over two sets of sites with site occupancies of 0.807 (6) and 0.193 (6). In the crystal, pairs of intermolecular N—H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers. |
format | Online Article Text |
id | pubmed-3213631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32136312011-11-16 N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide Pourayoubi, Mehrdad Saneei, Anahid Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent molecules in each of which the P atom adopts a distorted tetrahedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phosphoramide molecules are disordered over two sets of sites, with site occupancies of 0.766 (7) and 0.234 (7) for one ring and 0.639 (10) and 0.361 (10) for the other. In the second phosphoramide molecule, one of the NC(4)H(8)O moieties is disordered over two sets of sites with site occupancies of 0.807 (6) and 0.193 (6). In the crystal, pairs of intermolecular N—H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213631/ /pubmed/22091208 http://dx.doi.org/10.1107/S1600536811030194 Text en © Pourayoubi and Saneei 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pourayoubi, Mehrdad Saneei, Anahid N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title |
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title_full |
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title_fullStr |
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title_full_unstemmed |
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title_short |
N-[Bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
title_sort | n-[bis(morpholin-4-yl)phosphinoyl]-2-chloro-2,2-difluoroacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213631/ https://www.ncbi.nlm.nih.gov/pubmed/22091208 http://dx.doi.org/10.1107/S1600536811030194 |
work_keys_str_mv | AT pourayoubimehrdad nbismorpholin4ylphosphinoyl2chloro22difluoroacetamide AT saneeianahid nbismorpholin4ylphosphinoyl2chloro22difluoroacetamide |