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N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide

The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent mol­ecules in each of which the P atom adopts a distorted tetra­hedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phosph...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Saneei, Anahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213631/
https://www.ncbi.nlm.nih.gov/pubmed/22091208
http://dx.doi.org/10.1107/S1600536811030194
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author Pourayoubi, Mehrdad
Saneei, Anahid
author_facet Pourayoubi, Mehrdad
Saneei, Anahid
author_sort Pourayoubi, Mehrdad
collection PubMed
description The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent mol­ecules in each of which the P atom adopts a distorted tetra­hedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phospho­ramide mol­ecules are disordered over two sets of sites, with site occupancies of 0.766 (7) and 0.234 (7) for one ring and 0.639 (10) and 0.361 (10) for the other. In the second phospho­ramide mol­ecule, one of the NC(4)H(8)O moieties is disordered over two sets of sites with site occupancies of 0.807 (6) and 0.193 (6). In the crystal, pairs of inter­molecular N—H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers.
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spelling pubmed-32136312011-11-16 N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide Pourayoubi, Mehrdad Saneei, Anahid Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(17)ClF(2)N(3)O(4)P, consists of two independent mol­ecules in each of which the P atom adopts a distorted tetra­hedral environment with the P=O and N—H units in a syn orientation with respect to one another. Both morpholine rings in one of the phospho­ramide mol­ecules are disordered over two sets of sites, with site occupancies of 0.766 (7) and 0.234 (7) for one ring and 0.639 (10) and 0.361 (10) for the other. In the second phospho­ramide mol­ecule, one of the NC(4)H(8)O moieties is disordered over two sets of sites with site occupancies of 0.807 (6) and 0.193 (6). In the crystal, pairs of inter­molecular N—H⋯O(P) hydrogen bonds form two independent centrosymmetric dimers. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213631/ /pubmed/22091208 http://dx.doi.org/10.1107/S1600536811030194 Text en © Pourayoubi and Saneei 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Saneei, Anahid
N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title_full N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title_fullStr N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title_full_unstemmed N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title_short N-[Bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
title_sort n-[bis(morpholin-4-yl)phosphino­yl]-2-chloro-2,2-difluoro­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213631/
https://www.ncbi.nlm.nih.gov/pubmed/22091208
http://dx.doi.org/10.1107/S1600536811030194
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