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1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate

The mol­ecule of the title compound, C(66)H(40)F(6)·CH(2)Cl(2), is centrosymmetric; the dihedral angle between the central fluorinated unit and the cyclo­penta­diene ring is 88.36 (7)°. The dihedral angles between the cyclo­penta­diene ring and the four surrounding phenyl rings are in the range 26.6...

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Detalles Bibliográficos
Autor principal: Li, Shuhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213637/
https://www.ncbi.nlm.nih.gov/pubmed/22091214
http://dx.doi.org/10.1107/S1600536811030285
Descripción
Sumario:The mol­ecule of the title compound, C(66)H(40)F(6)·CH(2)Cl(2), is centrosymmetric; the dihedral angle between the central fluorinated unit and the cyclo­penta­diene ring is 88.36 (7)°. The dihedral angles between the cyclo­penta­diene ring and the four surrounding phenyl rings are in the range 26.6 (1)–65.6 (1)°. Centrosymmetric cavities in the crystal structure are populated by disordered dichloro­methane solvent mol­ecules.