1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate

The mol­ecule of the title compound, C(66)H(40)F(6)·CH(2)Cl(2), is centrosymmetric; the dihedral angle between the central fluorinated unit and the cyclo­penta­diene ring is 88.36 (7)°. The dihedral angles between the cyclo­penta­diene ring and the four surrounding phenyl rings are in the range 26.6...

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Detalles Bibliográficos
Autor principal: Li, Shuhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213637/
https://www.ncbi.nlm.nih.gov/pubmed/22091214
http://dx.doi.org/10.1107/S1600536811030285
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author Li, Shuhong
author_facet Li, Shuhong
author_sort Li, Shuhong
collection PubMed
description The mol­ecule of the title compound, C(66)H(40)F(6)·CH(2)Cl(2), is centrosymmetric; the dihedral angle between the central fluorinated unit and the cyclo­penta­diene ring is 88.36 (7)°. The dihedral angles between the cyclo­penta­diene ring and the four surrounding phenyl rings are in the range 26.6 (1)–65.6 (1)°. Centrosymmetric cavities in the crystal structure are populated by disordered dichloro­methane solvent mol­ecules.
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spelling pubmed-32136372011-11-16 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate Li, Shuhong Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(66)H(40)F(6)·CH(2)Cl(2), is centrosymmetric; the dihedral angle between the central fluorinated unit and the cyclo­penta­diene ring is 88.36 (7)°. The dihedral angles between the cyclo­penta­diene ring and the four surrounding phenyl rings are in the range 26.6 (1)–65.6 (1)°. Centrosymmetric cavities in the crystal structure are populated by disordered dichloro­methane solvent mol­ecules. International Union of Crystallography 2011-07-30 /pmc/articles/PMC3213637/ /pubmed/22091214 http://dx.doi.org/10.1107/S1600536811030285 Text en © Shuhong Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Shuhong
1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title_full 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title_fullStr 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title_full_unstemmed 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title_short 1′,3′,4′,5′,7′,8′-Hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
title_sort 1′,3′,4′,5′,7′,8′-hexafluoro-1,1′′,2,2′′,3,3′′,4,4′′-octa­phenyl-2′,6′-dihydro­dispiro­[cyclo­penta-1,3-diene-5,2′-naphthalene-6′,5′′-cyclo­penta-1′′,3′′-diene] dichloro­methane monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3213637/
https://www.ncbi.nlm.nih.gov/pubmed/22091214
http://dx.doi.org/10.1107/S1600536811030285
work_keys_str_mv AT lishuhong 134578hexafluoro11223344octaphenyl26dihydrodispirocyclopenta13diene52naphthalene65cyclopenta13dienedichloromethanemonosolvate

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