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Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase

A novel potential treatment technique applied to a glucose biosensor that is based on pyrroloquinoline quinone (PQQ)-dependent glucose dehydrogenase (GDH) and chromium hexacyanoferrate (CrHCF) incorporated into a platinum (Pt) electrode was demonstrated. CrHCF, serving as a mediator, was electrochem...

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Autores principales: Tseng, Ta-Feng, Yang, Yang-Li, Lin, Yuh-Jiuan, Lou, Shyh-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3231120/
https://www.ncbi.nlm.nih.gov/pubmed/22163553
http://dx.doi.org/10.3390/s100706347
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author Tseng, Ta-Feng
Yang, Yang-Li
Lin, Yuh-Jiuan
Lou, Shyh-Liang
author_facet Tseng, Ta-Feng
Yang, Yang-Li
Lin, Yuh-Jiuan
Lou, Shyh-Liang
author_sort Tseng, Ta-Feng
collection PubMed
description A novel potential treatment technique applied to a glucose biosensor that is based on pyrroloquinoline quinone (PQQ)-dependent glucose dehydrogenase (GDH) and chromium hexacyanoferrate (CrHCF) incorporated into a platinum (Pt) electrode was demonstrated. CrHCF, serving as a mediator, was electrochemically deposited on the Pt electrode as ascertained by CV, SEM, FTIR and XPS measurements. The potential treatment of CrHCF, which converts Fe(II) to Fe(III), enables the glucose detection. The amperometric measurement linearity of the biosensor was up to 20 mM (R = 0.9923), and the detection sensitivity was 199.94 nA/mM per cm(2). More importantly, this biosensor remained stable for >270 days.
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spelling pubmed-32311202011-12-07 Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase Tseng, Ta-Feng Yang, Yang-Li Lin, Yuh-Jiuan Lou, Shyh-Liang Sensors (Basel) Article A novel potential treatment technique applied to a glucose biosensor that is based on pyrroloquinoline quinone (PQQ)-dependent glucose dehydrogenase (GDH) and chromium hexacyanoferrate (CrHCF) incorporated into a platinum (Pt) electrode was demonstrated. CrHCF, serving as a mediator, was electrochemically deposited on the Pt electrode as ascertained by CV, SEM, FTIR and XPS measurements. The potential treatment of CrHCF, which converts Fe(II) to Fe(III), enables the glucose detection. The amperometric measurement linearity of the biosensor was up to 20 mM (R = 0.9923), and the detection sensitivity was 199.94 nA/mM per cm(2). More importantly, this biosensor remained stable for >270 days. Molecular Diversity Preservation International (MDPI) 2010-06-28 /pmc/articles/PMC3231120/ /pubmed/22163553 http://dx.doi.org/10.3390/s100706347 Text en © 2010 by the authors licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Tseng, Ta-Feng
Yang, Yang-Li
Lin, Yuh-Jiuan
Lou, Shyh-Liang
Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title_full Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title_fullStr Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title_full_unstemmed Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title_short Effects of Electric Potential Treatment of a Chromium Hexacyanoferrate Modified Biosensor Based on PQQ-Dependent Glucose Dehydrogenase
title_sort effects of electric potential treatment of a chromium hexacyanoferrate modified biosensor based on pqq-dependent glucose dehydrogenase
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3231120/
https://www.ncbi.nlm.nih.gov/pubmed/22163553
http://dx.doi.org/10.3390/s100706347
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