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Regioselectivity of H Cluster Oxidation
[Image: see text] The H(2)-evolving potential of [FeFe] hydrogenases is severely limited by the oxygen sensitivity of this class of enzymes. Recent experimental studies on hydrogenase from C. reinhardtii point to O(2)-induced structural changes in the [Fe(4)S(4)] subsite of the H cluster. Here, we i...
Autores principales: | Bruska, Marta K., Stiebritz, Martin T., Reiher, Markus |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238416/ https://www.ncbi.nlm.nih.gov/pubmed/22106822 http://dx.doi.org/10.1021/ja209165r |
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