Cargando…
Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetrahedra, alternating with Mn and Sn at...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238579/ https://www.ncbi.nlm.nih.gov/pubmed/22199470 http://dx.doi.org/10.1107/S1600536811047283 |
_version_ | 1782219014089474048 |
---|---|
author | Assoud, Abdeljalil Kuropatwa, Bryan A. Kleinke, Holger |
author_facet | Assoud, Abdeljalil Kuropatwa, Bryan A. Kleinke, Holger |
author_sort | Assoud, Abdeljalil |
collection | PubMed |
description | The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetrahedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two on twofold rotation axes, and exhibit distorted square-antiprismatic coordinations. |
format | Online Article Text |
id | pubmed-3238579 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32385792011-12-23 Barium manganese(II) selenostannate(IV), BaMnSnSe(4) Assoud, Abdeljalil Kuropatwa, Bryan A. Kleinke, Holger Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetrahedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two on twofold rotation axes, and exhibit distorted square-antiprismatic coordinations. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238579/ /pubmed/22199470 http://dx.doi.org/10.1107/S1600536811047283 Text en © Assoud et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Assoud, Abdeljalil Kuropatwa, Bryan A. Kleinke, Holger Barium manganese(II) selenostannate(IV), BaMnSnSe(4) |
title | Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
|
title_full | Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
|
title_fullStr | Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
|
title_full_unstemmed | Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
|
title_short | Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
|
title_sort | barium manganese(ii) selenostannate(iv), bamnsnse(4) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238579/ https://www.ncbi.nlm.nih.gov/pubmed/22199470 http://dx.doi.org/10.1107/S1600536811047283 |
work_keys_str_mv | AT assoudabdeljalil bariummanganeseiiselenostannateivbamnsnse4 AT kuropatwabryana bariummanganeseiiselenostannateivbamnsnse4 AT kleinkeholger bariummanganeseiiselenostannateivbamnsnse4 |