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Barium manganese(II) selenostannate(IV), BaMnSnSe(4)

The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetra­hedra, alternating with Mn and Sn at...

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Detalles Bibliográficos
Autores principales: Assoud, Abdeljalil, Kuropatwa, Bryan A., Kleinke, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238579/
https://www.ncbi.nlm.nih.gov/pubmed/22199470
http://dx.doi.org/10.1107/S1600536811047283
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author Assoud, Abdeljalil
Kuropatwa, Bryan A.
Kleinke, Holger
author_facet Assoud, Abdeljalil
Kuropatwa, Bryan A.
Kleinke, Holger
author_sort Assoud, Abdeljalil
collection PubMed
description The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetra­hedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two on twofold rotation axes, and exhibit distorted square-antiprismatic coordinations.
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spelling pubmed-32385792011-12-23 Barium manganese(II) selenostannate(IV), BaMnSnSe(4) Assoud, Abdeljalil Kuropatwa, Bryan A. Kleinke, Holger Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, BaMnSnSe(4), was obtained by reaction of the elements at 1123 K in an evacuated silica tube. It adopts the BaCdSnS(4) structure type, which is a variant of the SrIn(2)Se(4) structure type. Its structure consists of distorted edge-sharing tetra­hedra, alternating with Mn and Sn atoms as central atom. These [MnSnSe(6)] units display corner sharing, forming stacked infinite layers in the ac plane. The three different Ba(2+) atoms are located between the [MnSnSe(6)] layers, two on twofold rotation axes, and exhibit distorted square-antiprismatic coordinations. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238579/ /pubmed/22199470 http://dx.doi.org/10.1107/S1600536811047283 Text en © Assoud et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Assoud, Abdeljalil
Kuropatwa, Bryan A.
Kleinke, Holger
Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title_full Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title_fullStr Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title_full_unstemmed Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title_short Barium manganese(II) selenostannate(IV), BaMnSnSe(4)
title_sort barium manganese(ii) selenostannate(iv), bamnsnse(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238579/
https://www.ncbi.nlm.nih.gov/pubmed/22199470
http://dx.doi.org/10.1107/S1600536811047283
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AT kleinkeholger bariummanganeseiiselenostannateivbamnsnse4