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Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo)
The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric molecules in the unit cell (an invers...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238583/ https://www.ncbi.nlm.nih.gov/pubmed/22199474 http://dx.doi.org/10.1107/S1600536811044680 |
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author | Moroz, Yurii S. Cozzolino, Anthony F. Rybak-Akimova, Elena V. Cummins, Christopher C. |
author_facet | Moroz, Yurii S. Cozzolino, Anthony F. Rybak-Akimova, Elena V. Cummins, Christopher C. |
author_sort | Moroz, Yurii S. |
collection | PubMed |
description | The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric molecules in the unit cell (an inversion center is localized at the mid-point of the Mo—Mo bond), each with approximate non-crystallographic C (2h) symmetry. The molecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on different anilido ligands; the major component having an occupancy of 0.683 (7). The complex was obtained in low yield as the product from the reaction between the bridging pyrazine adduct of molybdenum tris-anilide ([μ(2)-(C(4)H(4)N(2)){Mo(C(11)H(16)N)(3)}(2)]) and mesityl nitrile with a loss of one anilido ligand. |
format | Online Article Text |
id | pubmed-3238583 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32385832011-12-23 Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) Moroz, Yurii S. Cozzolino, Anthony F. Rybak-Akimova, Elena V. Cummins, Christopher C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric molecules in the unit cell (an inversion center is localized at the mid-point of the Mo—Mo bond), each with approximate non-crystallographic C (2h) symmetry. The molecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on different anilido ligands; the major component having an occupancy of 0.683 (7). The complex was obtained in low yield as the product from the reaction between the bridging pyrazine adduct of molybdenum tris-anilide ([μ(2)-(C(4)H(4)N(2)){Mo(C(11)H(16)N)(3)}(2)]) and mesityl nitrile with a loss of one anilido ligand. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238583/ /pubmed/22199474 http://dx.doi.org/10.1107/S1600536811044680 Text en © Moroz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Moroz, Yurii S. Cozzolino, Anthony F. Rybak-Akimova, Elena V. Cummins, Christopher C. Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title | Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title_full | Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title_fullStr | Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title_full_unstemmed | Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title_short | Bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) |
title_sort | bis(μ(2)-η(2):η(2)-2,4,6-trimethylbenzonitrile)bis[(n-isopropyl-3,5-dimethylanilido)molybdenum(iii)](mo—mo) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238583/ https://www.ncbi.nlm.nih.gov/pubmed/22199474 http://dx.doi.org/10.1107/S1600536811044680 |
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