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Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)

The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol­ecules in the unit cell (an invers...

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Autores principales: Moroz, Yurii S., Cozzolino, Anthony F., Rybak-Akimova, Elena V., Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238583/
https://www.ncbi.nlm.nih.gov/pubmed/22199474
http://dx.doi.org/10.1107/S1600536811044680
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author Moroz, Yurii S.
Cozzolino, Anthony F.
Rybak-Akimova, Elena V.
Cummins, Christopher C.
author_facet Moroz, Yurii S.
Cozzolino, Anthony F.
Rybak-Akimova, Elena V.
Cummins, Christopher C.
author_sort Moroz, Yurii S.
collection PubMed
description The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol­ecules in the unit cell (an inversion center is localized at the mid-point of the Mo—Mo bond), each with approximate non-crystallographic C (2h) symmetry. The mol­ecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on different anilido ligands; the major component having an occupancy of 0.683 (7). The complex was obtained in low yield as the product from the reaction between the bridging pyrazine adduct of molybdenum tris­-anilide ([μ(2)-(C(4)H(4)N(2)){Mo(C(11)H(16)N)(3)}(2)]) and mesityl nitrile with a loss of one anilido ligand.
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spelling pubmed-32385832011-12-23 Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo) Moroz, Yurii S. Cozzolino, Anthony F. Rybak-Akimova, Elena V. Cummins, Christopher C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal–metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol­ecules in the unit cell (an inversion center is localized at the mid-point of the Mo—Mo bond), each with approximate non-crystallographic C (2h) symmetry. The mol­ecules contain disordered isopropyl and 3,5-C(6)H(3)Me(2) groups on different anilido ligands; the major component having an occupancy of 0.683 (7). The complex was obtained in low yield as the product from the reaction between the bridging pyrazine adduct of molybdenum tris­-anilide ([μ(2)-(C(4)H(4)N(2)){Mo(C(11)H(16)N)(3)}(2)]) and mesityl nitrile with a loss of one anilido ligand. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238583/ /pubmed/22199474 http://dx.doi.org/10.1107/S1600536811044680 Text en © Moroz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moroz, Yurii S.
Cozzolino, Anthony F.
Rybak-Akimova, Elena V.
Cummins, Christopher C.
Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title_full Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title_fullStr Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title_full_unstemmed Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title_short Bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(N-isopropyl-3,5-dimethyl­anilido)molybdenum(III)](Mo—Mo)
title_sort bis(μ(2)-η(2):η(2)-2,4,6-trimethyl­benzonitrile)­bis­[(n-isopropyl-3,5-dimethyl­anilido)molybdenum(iii)](mo—mo)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238583/
https://www.ncbi.nlm.nih.gov/pubmed/22199474
http://dx.doi.org/10.1107/S1600536811044680
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