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Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc
In the title compound, [Zn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the six-coordinate Zn(II) ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the Zn(II) ion through a tr...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238584/ https://www.ncbi.nlm.nih.gov/pubmed/22199475 http://dx.doi.org/10.1107/S160053681104387X |
Sumario: | In the title compound, [Zn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the six-coordinate Zn(II) ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the Zn(II) ion through a triazole N atom and a carboxylate O atom in the equatorial plane. The coordination sphere is completed by two water molecules in axial positions. There is an intramolecular O—H⋯O hydrogen bond in the ligand. In the crystal, molecules are linked via intermolecular O—H⋯O, O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional structure. |
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