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Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc
In the title compound, [Zn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the six-coordinate Zn(II) ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the Zn(II) ion through a tr...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238584/ https://www.ncbi.nlm.nih.gov/pubmed/22199475 http://dx.doi.org/10.1107/S160053681104387X |
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author | Hao, Jing-Hao Wang, Jian-Ling |
author_facet | Hao, Jing-Hao Wang, Jian-Ling |
author_sort | Hao, Jing-Hao |
collection | PubMed |
description | In the title compound, [Zn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the six-coordinate Zn(II) ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the Zn(II) ion through a triazole N atom and a carboxylate O atom in the equatorial plane. The coordination sphere is completed by two water molecules in axial positions. There is an intramolecular O—H⋯O hydrogen bond in the ligand. In the crystal, molecules are linked via intermolecular O—H⋯O, O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3238584 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32385842011-12-23 Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc Hao, Jing-Hao Wang, Jian-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(6)N(5)O(4))(2)(H(2)O)(2)], the six-coordinate Zn(II) ion, which is located on an inversion center, has a distorted octahedral configuration. Each 5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylate ligand chelates to the Zn(II) ion through a triazole N atom and a carboxylate O atom in the equatorial plane. The coordination sphere is completed by two water molecules in axial positions. There is an intramolecular O—H⋯O hydrogen bond in the ligand. In the crystal, molecules are linked via intermolecular O—H⋯O, O—H⋯N and N—H⋯N hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238584/ /pubmed/22199475 http://dx.doi.org/10.1107/S160053681104387X Text en © Hao and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hao, Jing-Hao Wang, Jian-Ling Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title | Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title_full | Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title_fullStr | Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title_full_unstemmed | Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title_short | Diaquabis{5-carboxy-2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-imidazole-4-carboxylato}zinc |
title_sort | diaquabis{5-carboxy-2-[(1h-1,2,4-triazol-1-yl)methyl]-1h-imidazole-4-carboxylato}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238584/ https://www.ncbi.nlm.nih.gov/pubmed/22199475 http://dx.doi.org/10.1107/S160053681104387X |
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