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4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate

In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octa­hedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water mol­ecules in axial positions. An...

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Autores principales: Chérif, Ichraf, Abdelhak, Jawher, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238586/
https://www.ncbi.nlm.nih.gov/pubmed/22199477
http://dx.doi.org/10.1107/S1600536811044837
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author Chérif, Ichraf
Abdelhak, Jawher
Zid, Mohamed Faouzi
Driss, Ahmed
author_facet Chérif, Ichraf
Abdelhak, Jawher
Zid, Mohamed Faouzi
Driss, Ahmed
author_sort Chérif, Ichraf
collection PubMed
description In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octa­hedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water mol­ecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water mol­ecules, the 4-amino­pyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π inter­actions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å.
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spelling pubmed-32385862011-12-23 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate Chérif, Ichraf Abdelhak, Jawher Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octa­hedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water mol­ecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water mol­ecules, the 4-amino­pyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π inter­actions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238586/ /pubmed/22199477 http://dx.doi.org/10.1107/S1600536811044837 Text en © Chérif et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chérif, Ichraf
Abdelhak, Jawher
Zid, Mohamed Faouzi
Driss, Ahmed
4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title_full 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title_fullStr 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title_full_unstemmed 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title_short 4-Amino­pyridinium trans-diaqua­dioxalatochromate(III) monohydrate
title_sort 4-amino­pyridinium trans-diaqua­dioxalatochromate(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238586/
https://www.ncbi.nlm.nih.gov/pubmed/22199477
http://dx.doi.org/10.1107/S1600536811044837
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