Cargando…
4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate
In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238586/ https://www.ncbi.nlm.nih.gov/pubmed/22199477 http://dx.doi.org/10.1107/S1600536811044837 |
_version_ | 1782219015693795328 |
---|---|
author | Chérif, Ichraf Abdelhak, Jawher Zid, Mohamed Faouzi Driss, Ahmed |
author_facet | Chérif, Ichraf Abdelhak, Jawher Zid, Mohamed Faouzi Driss, Ahmed |
author_sort | Chérif, Ichraf |
collection | PubMed |
description | In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water molecules, the 4-aminopyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π interactions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å. |
format | Online Article Text |
id | pubmed-3238586 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32385862011-12-23 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate Chérif, Ichraf Abdelhak, Jawher Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the non-centrosymmetric structure of the title compound, (C(5)H(7)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·H(2)O, the Cr(III) ion has a slightly distorted octahedral coordination environment defined by two chelating oxalato ligands in equatorial positions and two water molecules in axial positions. An extensive three-dimensional network of hydrogen bonds involving all the water molecules, the 4-aminopyridinium cation and some of the oxalate O atoms contributes to the stabilization of the structure. π–π interactions between adjacent pyridine rings provide additional stability of the crystal packing, with a closest distance between pyridine mean planes of 3.613 (1) Å. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238586/ /pubmed/22199477 http://dx.doi.org/10.1107/S1600536811044837 Text en © Chérif et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chérif, Ichraf Abdelhak, Jawher Zid, Mohamed Faouzi Driss, Ahmed 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title | 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title_full | 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title_fullStr | 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title_full_unstemmed | 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title_short | 4-Aminopyridinium trans-diaquadioxalatochromate(III) monohydrate |
title_sort | 4-aminopyridinium trans-diaquadioxalatochromate(iii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238586/ https://www.ncbi.nlm.nih.gov/pubmed/22199477 http://dx.doi.org/10.1107/S1600536811044837 |
work_keys_str_mv | AT cherifichraf 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate AT abdelhakjawher 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate AT zidmohamedfaouzi 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate AT drissahmed 4aminopyridiniumtransdiaquadioxalatochromateiiimonohydrate |