(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium

In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a d...

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Detalles Bibliográficos
Autores principales: Warad, Ismail, Boshaala, Ahmed, Al-Resayes, Saud I., Al-Deyab, Salem S., Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238587/
https://www.ncbi.nlm.nih.gov/pubmed/22199478
http://dx.doi.org/10.1107/S1600536811044667
Descripción
Sumario:In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra­hedral geometry. Inversion-related mol­ecules inter­act along the c-axis direction by π–π stacking inter­actions between the phenanthroline ring systems, with centroid–centroid distances of 3.707 (9) and 3.597 (10) Å.

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