(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium

In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a d...

Descripción completa

Detalles Bibliográficos
Autores principales: Warad, Ismail, Boshaala, Ahmed, Al-Resayes, Saud I., Al-Deyab, Salem S., Rzaigui, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238587/
https://www.ncbi.nlm.nih.gov/pubmed/22199478
http://dx.doi.org/10.1107/S1600536811044667
_version_ 1782219015916093440
author Warad, Ismail
Boshaala, Ahmed
Al-Resayes, Saud I.
Al-Deyab, Salem S.
Rzaigui, Mohamed
author_facet Warad, Ismail
Boshaala, Ahmed
Al-Resayes, Saud I.
Al-Deyab, Salem S.
Rzaigui, Mohamed
author_sort Warad, Ismail
collection PubMed
description In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra­hedral geometry. Inversion-related mol­ecules inter­act along the c-axis direction by π–π stacking inter­actions between the phenanthroline ring systems, with centroid–centroid distances of 3.707 (9) and 3.597 (10) Å.
format Online
Article
Text
id pubmed-3238587
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32385872011-12-23 (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium Warad, Ismail Boshaala, Ahmed Al-Resayes, Saud I. Al-Deyab, Salem S. Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol­ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra­hedral geometry. Inversion-related mol­ecules inter­act along the c-axis direction by π–π stacking inter­actions between the phenanthroline ring systems, with centroid–centroid distances of 3.707 (9) and 3.597 (10) Å. International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238587/ /pubmed/22199478 http://dx.doi.org/10.1107/S1600536811044667 Text en © Warad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warad, Ismail
Boshaala, Ahmed
Al-Resayes, Saud I.
Al-Deyab, Salem S.
Rzaigui, Mohamed
(2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title_full (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title_fullStr (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title_full_unstemmed (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title_short (2,9-Dimethyl-1,10-phenanthroline-κ(2) N,N′)diiodidocadmium
title_sort (2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)diiodidocadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238587/
https://www.ncbi.nlm.nih.gov/pubmed/22199478
http://dx.doi.org/10.1107/S1600536811044667
work_keys_str_mv AT waradismail 29dimethyl110phenanthrolinek2nndiiodidocadmium
AT boshaalaahmed 29dimethyl110phenanthrolinek2nndiiodidocadmium
AT alresayessaudi 29dimethyl110phenanthrolinek2nndiiodidocadmium
AT aldeyabsalems 29dimethyl110phenanthrolinek2nndiiodidocadmium
AT rzaiguimohamed 29dimethyl110phenanthrolinek2nndiiodidocadmium

Ejemplares similares