trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)

In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50 (9), 75.51 (10) and 80.63 (10)° with...

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Autores principales: Norlidah, M. N., Yazid, M. Y., Shawkataly, Omar bin, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238589/
https://www.ncbi.nlm.nih.gov/pubmed/22199480
http://dx.doi.org/10.1107/S1600536811045284
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author Norlidah, M. N.
Yazid, M. Y.
Shawkataly, Omar bin
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Norlidah, M. N.
Yazid, M. Y.
Shawkataly, Omar bin
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Norlidah, M. N.
collection PubMed
description In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50 (9), 75.51 (10) and 80.63 (10)° with each other, while in the other ligand these angles are 51.92 (10), 78.56 (11) and 86.80 (10)°. C—H⋯O and C—H⋯F inter­actions link the mol­ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944 (3):0.056 (3), 0.702 (4):0.298 (4), 0.829 (4):0.171 (4), 0.567 (4):0.433 (4), 0.545 (4):0.455 (4) and 0.920 (4):0.080 (4).
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spelling pubmed-32385892011-12-23 trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0) Norlidah, M. N. Yazid, M. Y. Shawkataly, Omar bin Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa­hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50 (9), 75.51 (10) and 80.63 (10)° with each other, while in the other ligand these angles are 51.92 (10), 78.56 (11) and 86.80 (10)°. C—H⋯O and C—H⋯F inter­actions link the mol­ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944 (3):0.056 (3), 0.702 (4):0.298 (4), 0.829 (4):0.171 (4), 0.567 (4):0.433 (4), 0.545 (4):0.455 (4) and 0.920 (4):0.080 (4). International Union of Crystallography 2011-11-02 /pmc/articles/PMC3238589/ /pubmed/22199480 http://dx.doi.org/10.1107/S1600536811045284 Text en © Norlidah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Norlidah, M. N.
Yazid, M. Y.
Shawkataly, Omar bin
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title_full trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title_fullStr trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title_full_unstemmed trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title_short trans-Tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
title_sort trans-tetra­carbonyl­bis­[tris­(3-fluoro­phen­yl)phosphane]chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238589/
https://www.ncbi.nlm.nih.gov/pubmed/22199480
http://dx.doi.org/10.1107/S1600536811045284
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AT shawkatalyomarbin transtetracarbonylbistris3fluorophenylphosphanechromium0
AT roslimohdmustaqim transtetracarbonylbistris3fluorophenylphosphanechromium0
AT funhoongkun transtetracarbonylbistris3fluorophenylphosphanechromium0

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