catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]

In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra­hadral LiO(4) coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], g...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D., Williams, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238593/
https://www.ncbi.nlm.nih.gov/pubmed/22199484
http://dx.doi.org/10.1107/S1600536811045077
Descripción
Sumario:In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra­hadral LiO(4) coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], giving chain substructures which extend along [010]. Water–water and water–carboxyl O—H⋯O hydrogen bonds stabilize these chain structures and provide inter­chain links, resulting in a two-dimensional layered structure extending parallel to (100).

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