catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]

In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra­hadral LiO(4) coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], g...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D., Williams, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238593/
https://www.ncbi.nlm.nih.gov/pubmed/22199484
http://dx.doi.org/10.1107/S1600536811045077
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author Smith, Graham
Wermuth, Urs D.
Williams, Michael L.
author_facet Smith, Graham
Wermuth, Urs D.
Williams, Michael L.
author_sort Smith, Graham
collection PubMed
description In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra­hadral LiO(4) coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], giving chain substructures which extend along [010]. Water–water and water–carboxyl O—H⋯O hydrogen bonds stabilize these chain structures and provide inter­chain links, resulting in a two-dimensional layered structure extending parallel to (100).
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spelling pubmed-32385932011-12-23 catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]] Smith, Graham Wermuth, Urs D. Williams, Michael L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra­hadral LiO(4) coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], giving chain substructures which extend along [010]. Water–water and water–carboxyl O—H⋯O hydrogen bonds stabilize these chain structures and provide inter­chain links, resulting in a two-dimensional layered structure extending parallel to (100). International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238593/ /pubmed/22199484 http://dx.doi.org/10.1107/S1600536811045077 Text en © Smith et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Smith, Graham
Wermuth, Urs D.
Williams, Michael L.
catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title_full catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title_fullStr catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title_full_unstemmed catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title_short catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) O (1):O (2)]]
title_sort catena-poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ(2) o (1):o (2)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238593/
https://www.ncbi.nlm.nih.gov/pubmed/22199484
http://dx.doi.org/10.1107/S1600536811045077
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