trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)

In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0...

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Detalles Bibliográficos
Autor principal: Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238597/
https://www.ncbi.nlm.nih.gov/pubmed/22199488
http://dx.doi.org/10.1107/S1600536811044795
Descripción
Sumario:In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0.304 (15) ratio.

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