trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)

In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0...

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Detalles Bibliográficos
Autor principal: Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238597/
https://www.ncbi.nlm.nih.gov/pubmed/22199488
http://dx.doi.org/10.1107/S1600536811044795
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author Meijboom, Reinout
author_facet Meijboom, Reinout
author_sort Meijboom, Reinout
collection PubMed
description In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0.304 (15) ratio.
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spelling pubmed-32385972011-12-23 trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II) Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd—P and Pd—Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0.304 (15) ratio. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238597/ /pubmed/22199488 http://dx.doi.org/10.1107/S1600536811044795 Text en © Reinout Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meijboom, Reinout
trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title_full trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title_fullStr trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title_full_unstemmed trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title_short trans-Dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κP]palladium(II)
title_sort trans-dichloridobis[diphen­yl(4-vinyl­phen­yl)phosphane-κp]palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238597/
https://www.ncbi.nlm.nih.gov/pubmed/22199488
http://dx.doi.org/10.1107/S1600536811044795
work_keys_str_mv AT meijboomreinout transdichloridobisdiphenyl4vinylphenylphosphanekppalladiumii

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