trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)

In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a ce...

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Detalles Bibliográficos
Autores principales: Warsink, Stefan, Koen, Renier, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238600/
https://www.ncbi.nlm.nih.gov/pubmed/22199491
http://dx.doi.org/10.1107/S1600536811045715
Descripción
Sumario:In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a center of inversion. The effective cone angle Θ(E) for the title compound is 169.0 (3)°. There are no significant inter­molecular inter­actions.

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