trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)

In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a ce...

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Detalles Bibliográficos
Autores principales: Warsink, Stefan, Koen, Renier, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238600/
https://www.ncbi.nlm.nih.gov/pubmed/22199491
http://dx.doi.org/10.1107/S1600536811045715
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author Warsink, Stefan
Koen, Renier
Roodt, Andreas
author_facet Warsink, Stefan
Koen, Renier
Roodt, Andreas
author_sort Warsink, Stefan
collection PubMed
description In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a center of inversion. The effective cone angle Θ(E) for the title compound is 169.0 (3)°. There are no significant inter­molecular inter­actions.
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spelling pubmed-32386002011-12-23 trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I) Warsink, Stefan Koen, Renier Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RhCl(C(21)H(21)P)(2)(CO)], the coordination geometry around the Rh(I) atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the Rh(I) atom lies on a center of inversion. The effective cone angle Θ(E) for the title compound is 169.0 (3)°. There are no significant inter­molecular inter­actions. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238600/ /pubmed/22199491 http://dx.doi.org/10.1107/S1600536811045715 Text en © Warsink et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warsink, Stefan
Koen, Renier
Roodt, Andreas
trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title_full trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title_fullStr trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title_full_unstemmed trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title_short trans-Carbonyl­chloridobis(tri-o-tolyl­phosphane-κP)rhodium(I)
title_sort trans-carbonyl­chloridobis(tri-o-tolyl­phosphane-κp)rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238600/
https://www.ncbi.nlm.nih.gov/pubmed/22199491
http://dx.doi.org/10.1107/S1600536811045715
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AT roodtandreas transcarbonylchloridobistriotolylphosphanekprhodiumi

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