Cargando…

[1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate

In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis­(diphenyl­phosphan­yl)cobaltocenium ligand and a triphenyl­phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa­hed...

Descripción completa

Detalles Bibliográficos
Autor principal: Hou, Jian-Guo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238603/
https://www.ncbi.nlm.nih.gov/pubmed/22199494
http://dx.doi.org/10.1107/S1600536811044035
_version_ 1782219019554652160
author Hou, Jian-Guo
author_facet Hou, Jian-Guo
author_sort Hou, Jian-Guo
collection PubMed
description In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis­(diphenyl­phosphan­yl)cobaltocenium ligand and a triphenyl­phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa­hedral geometry. In the cobaltocenium unit, the two cyclo­penta­dienyl rings are almost parallel, making a dihedral angle of 1.2 (3)°. The F atoms of the hexa­fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849 (11):0.151 (11). Intra­molecular C—H⋯Cl hydrogen bonds occur in the complex cation. The complex cations, hexa­fluoridophosphate anions and dichloro­methane solvent mol­ecules are linked by inter­molecular C—H⋯F hydrogen bonds.
format Online
Article
Text
id pubmed-3238603
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386032011-12-23 [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate Hou, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis­(diphenyl­phosphan­yl)cobaltocenium ligand and a triphenyl­phosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octa­hedral geometry. In the cobaltocenium unit, the two cyclo­penta­dienyl rings are almost parallel, making a dihedral angle of 1.2 (3)°. The F atoms of the hexa­fluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849 (11):0.151 (11). Intra­molecular C—H⋯Cl hydrogen bonds occur in the complex cation. The complex cations, hexa­fluoridophosphate anions and dichloro­methane solvent mol­ecules are linked by inter­molecular C—H⋯F hydrogen bonds. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238603/ /pubmed/22199494 http://dx.doi.org/10.1107/S1600536811044035 Text en © Jian-Guo Hou 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hou, Jian-Guo
[1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title_full [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title_fullStr [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title_full_unstemmed [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title_short [1,1′-Bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(II) hexa­fluoridophosphate dichloro­methane disolvate
title_sort [1,1′-bis(diphenyl­phosphan­yl)cobalto­cenium]carbonyl­chloridohydrido(triphenyl­phosphane)ruthenium(ii) hexa­fluoridophosphate dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238603/
https://www.ncbi.nlm.nih.gov/pubmed/22199494
http://dx.doi.org/10.1107/S1600536811044035
work_keys_str_mv AT houjianguo 11bisdiphenylphosphanylcobaltoceniumcarbonylchloridohydridotriphenylphosphanerutheniumiihexafluoridophosphatedichloromethanedisolvate