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[1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate
In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis(diphenylphosphanyl)cobaltocenium ligand and a triphenylphosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octahed...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238603/ https://www.ncbi.nlm.nih.gov/pubmed/22199494 http://dx.doi.org/10.1107/S1600536811044035 |
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author | Hou, Jian-Guo |
author_facet | Hou, Jian-Guo |
author_sort | Hou, Jian-Guo |
collection | PubMed |
description | In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis(diphenylphosphanyl)cobaltocenium ligand and a triphenylphosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octahedral geometry. In the cobaltocenium unit, the two cyclopentadienyl rings are almost parallel, making a dihedral angle of 1.2 (3)°. The F atoms of the hexafluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849 (11):0.151 (11). Intramolecular C—H⋯Cl hydrogen bonds occur in the complex cation. The complex cations, hexafluoridophosphate anions and dichloromethane solvent molecules are linked by intermolecular C—H⋯F hydrogen bonds. |
format | Online Article Text |
id | pubmed-3238603 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386032011-12-23 [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate Hou, Jian-Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoRu(C(17)H(14)P)(2)ClH(C(18)H(15)P)(CO)]PF(6)·2CH(2)Cl(2), the Ru(II) atom is coordinated by three P atoms from a chelating 1,1′-bis(diphenylphosphanyl)cobaltocenium ligand and a triphenylphosphine ligand, one CO ligand, one Cl atom and one H atom in a distorted octahedral geometry. In the cobaltocenium unit, the two cyclopentadienyl rings are almost parallel, making a dihedral angle of 1.2 (3)°. The F atoms of the hexafluoridophosphate anion are disordered over two sets of sites, with an occupancy ratio of 0.849 (11):0.151 (11). Intramolecular C—H⋯Cl hydrogen bonds occur in the complex cation. The complex cations, hexafluoridophosphate anions and dichloromethane solvent molecules are linked by intermolecular C—H⋯F hydrogen bonds. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238603/ /pubmed/22199494 http://dx.doi.org/10.1107/S1600536811044035 Text en © Jian-Guo Hou 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hou, Jian-Guo [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title | [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title_full | [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title_fullStr | [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title_full_unstemmed | [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title_short | [1,1′-Bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(II) hexafluoridophosphate dichloromethane disolvate |
title_sort | [1,1′-bis(diphenylphosphanyl)cobaltocenium]carbonylchloridohydrido(triphenylphosphane)ruthenium(ii) hexafluoridophosphate dichloromethane disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238603/ https://www.ncbi.nlm.nih.gov/pubmed/22199494 http://dx.doi.org/10.1107/S1600536811044035 |
work_keys_str_mv | AT houjianguo 11bisdiphenylphosphanylcobaltoceniumcarbonylchloridohydridotriphenylphosphanerutheniumiihexafluoridophosphatedichloromethanedisolvate |