catena-Poly[[triphenyl­tin(IV)]-μ-phenyl­phosphinato-κ(2) O:O′]

In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O(2) (−) anions in apical positions. In the crystal,...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, Diop, Libasse, Kociok-Köhn, Gabriele, Molloy, Kieran C., Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238605/
https://www.ncbi.nlm.nih.gov/pubmed/22199496
http://dx.doi.org/10.1107/S1600536811043625
Descripción
Sumario:In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O(2) (−) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C—H⋯π inter­actions, forming a two-dimensional network lying parallel to (001).

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