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catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2) O:O′]
In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O(2) (−) anions in apical positions. In the crystal,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238605/ https://www.ncbi.nlm.nih.gov/pubmed/22199496 http://dx.doi.org/10.1107/S1600536811043625 |
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author | Diop, Tidiane Diop, Libasse Kociok-Köhn, Gabriele Molloy, Kieran C. Stoeckli-Evans, Helen |
author_facet | Diop, Tidiane Diop, Libasse Kociok-Köhn, Gabriele Molloy, Kieran C. Stoeckli-Evans, Helen |
author_sort | Diop, Tidiane |
collection | PubMed |
description | In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O(2) (−) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C—H⋯π interactions, forming a two-dimensional network lying parallel to (001). |
format | Online Article Text |
id | pubmed-3238605 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386052011-12-23 catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2) O:O′] Diop, Tidiane Diop, Libasse Kociok-Köhn, Gabriele Molloy, Kieran C. Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O(2) (−) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C—H⋯π interactions, forming a two-dimensional network lying parallel to (001). International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238605/ /pubmed/22199496 http://dx.doi.org/10.1107/S1600536811043625 Text en © Diop et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Diop, Tidiane Diop, Libasse Kociok-Köhn, Gabriele Molloy, Kieran C. Stoeckli-Evans, Helen catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2) O:O′] |
title |
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2)
O:O′] |
title_full |
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2)
O:O′] |
title_fullStr |
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2)
O:O′] |
title_full_unstemmed |
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2)
O:O′] |
title_short |
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ(2)
O:O′] |
title_sort | catena-poly[[triphenyltin(iv)]-μ-phenylphosphinato-κ(2)
o:o′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238605/ https://www.ncbi.nlm.nih.gov/pubmed/22199496 http://dx.doi.org/10.1107/S1600536811043625 |
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