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Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate

In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra­hedral geometry by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, one O atom from a trifluoro...

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Detalles Bibliográficos
Autores principales: Huang, Li-Li, Jia, Chen, Tang, Li-Ping, Jing, Bai, Deng, Qi-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238607/
https://www.ncbi.nlm.nih.gov/pubmed/22199498
http://dx.doi.org/10.1107/S1600536811045466
Descripción
Sumario:In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra­hedral geometry by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, one O atom from a trifluoro­acetate anion and two O atoms from two diphenyl­phosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoro­acetate anions bridge four metal atoms, forming a centrosymmetric tetra­nuclear complex. Intra­molecular C—H⋯O hydrogen bonds and a weak π–π inter­action [centroid–centroid distance = 3.9804 (13) Å] are also observed.