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Bis[μ(2)-bis(diphenylphosphanyl)methane-κ(2) P:P′]bis(μ(4)-diphenylphosphinato-κ(4) O:O:O′:O′)bis(μ(2)-trifluoroacetato-κ(2) O:O′)tetrasilver(I) acetonitrile disolvate
In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetrahedral geometry by one P atom from a bis(diphenylphosphanyl)methane (dppm) ligand, one O atom from a trifluoro...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238607/ https://www.ncbi.nlm.nih.gov/pubmed/22199498 http://dx.doi.org/10.1107/S1600536811045466 |
Sumario: | In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetrahedral geometry by one P atom from a bis(diphenylphosphanyl)methane (dppm) ligand, one O atom from a trifluoroacetate anion and two O atoms from two diphenylphosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoroacetate anions bridge four metal atoms, forming a centrosymmetric tetranuclear complex. Intramolecular C—H⋯O hydrogen bonds and a weak π–π interaction [centroid–centroid distance = 3.9804 (13) Å] are also observed. |
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