Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate

In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra­hedral geometry by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, one O atom from a trifluoro...

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Autores principales: Huang, Li-Li, Jia, Chen, Tang, Li-Ping, Jing, Bai, Deng, Qi-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238607/
https://www.ncbi.nlm.nih.gov/pubmed/22199498
http://dx.doi.org/10.1107/S1600536811045466
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author Huang, Li-Li
Jia, Chen
Tang, Li-Ping
Jing, Bai
Deng, Qi-Hua
author_facet Huang, Li-Li
Jia, Chen
Tang, Li-Ping
Jing, Bai
Deng, Qi-Hua
author_sort Huang, Li-Li
collection PubMed
description In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra­hedral geometry by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, one O atom from a trifluoro­acetate anion and two O atoms from two diphenyl­phosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoro­acetate anions bridge four metal atoms, forming a centrosymmetric tetra­nuclear complex. Intra­molecular C—H⋯O hydrogen bonds and a weak π–π inter­action [centroid–centroid distance = 3.9804 (13) Å] are also observed.
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spelling pubmed-32386072011-12-23 Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate Huang, Li-Li Jia, Chen Tang, Li-Ping Jing, Bai Deng, Qi-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Ag(4)(C(2)F(3)O(2))(2)(C(12)H(10)O(2)P)(2)(C(25)H(22)P(2))(2)]·2CH(3)CN, the two independent Ag(+) cations are four-coordinated in a distorted tetra­hedral geometry by one P atom from a bis­(diphenyl­phosphan­yl)methane (dppm) ligand, one O atom from a trifluoro­acetate anion and two O atoms from two diphenyl­phosphinate (dpp) ligands. Two dppm ligands, two dpp ligands and two trifluoro­acetate anions bridge four metal atoms, forming a centrosymmetric tetra­nuclear complex. Intra­molecular C—H⋯O hydrogen bonds and a weak π–π inter­action [centroid–centroid distance = 3.9804 (13) Å] are also observed. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238607/ /pubmed/22199498 http://dx.doi.org/10.1107/S1600536811045466 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Li-Li
Jia, Chen
Tang, Li-Ping
Jing, Bai
Deng, Qi-Hua
Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title_full Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title_fullStr Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title_full_unstemmed Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title_short Bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) P:P′]bis­(μ(4)-diphenyl­phosphinato-κ(4) O:O:O′:O′)bis­(μ(2)-trifluoro­acetato-κ(2) O:O′)tetra­silver(I) acetonitrile disolvate
title_sort bis[μ(2)-bis­(diphenyl­phosphan­yl)methane-κ(2) p:p′]bis­(μ(4)-diphenyl­phosphinato-κ(4) o:o:o′:o′)bis­(μ(2)-trifluoro­acetato-κ(2) o:o′)tetra­silver(i) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238607/
https://www.ncbi.nlm.nih.gov/pubmed/22199498
http://dx.doi.org/10.1107/S1600536811045466
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