Cargando…

Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]

In the title compound, {[Co(3)Lu(2)(C(5)H(2)N(2)O(4))(6)(H(2)O)(4)]·2H(2)O}(n), the Lu(III) ions are seven-coordinated in a monocapped trigonal prismatic coordination geometry by six O atoms from three imidazole-4,5-dicarboxyl­ate ligands and one water O atom. The Co(II) ions are six-coordinated in...

Descripción completa

Detalles Bibliográficos
Autor principal: Zhu, Li-Cai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238609/
https://www.ncbi.nlm.nih.gov/pubmed/22199500
http://dx.doi.org/10.1107/S1600536811045764
_version_ 1782219020947161088
author Zhu, Li-Cai
author_facet Zhu, Li-Cai
author_sort Zhu, Li-Cai
collection PubMed
description In the title compound, {[Co(3)Lu(2)(C(5)H(2)N(2)O(4))(6)(H(2)O)(4)]·2H(2)O}(n), the Lu(III) ions are seven-coordinated in a monocapped trigonal prismatic coordination geometry by six O atoms from three imidazole-4,5-dicarboxyl­ate ligands and one water O atom. The Co(II) ions are six-coordinated in a slightly distorted octa­hedral geometry and exhibit two types of coordination environments. One Co(II) ion, located on an inversion center, is coordinated by two water O atoms as well as two O atoms and two N atoms from two imidazole-4,5-dicarboxyl­ate ligands. The other Co(II) ion is bonded to four O atoms and two N atoms from four imidazole-4,5-dicarboxyl­ate ligands. These metal coordination units are connected by bridging imidazole-4,5-dicarboxyl­ate ligands, generating a three-dimensional network. The crystal structure is further stabilized by N—H⋯O, O—H⋯O, and C—H⋯O hydrogen-bonding inter­actions between the water mol­ecules and the imidazole-4,5-dicarboxyl­ate ligands.
format Online
Article
Text
id pubmed-3238609
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386092011-12-23 Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(3)Lu(2)(C(5)H(2)N(2)O(4))(6)(H(2)O)(4)]·2H(2)O}(n), the Lu(III) ions are seven-coordinated in a monocapped trigonal prismatic coordination geometry by six O atoms from three imidazole-4,5-dicarboxyl­ate ligands and one water O atom. The Co(II) ions are six-coordinated in a slightly distorted octa­hedral geometry and exhibit two types of coordination environments. One Co(II) ion, located on an inversion center, is coordinated by two water O atoms as well as two O atoms and two N atoms from two imidazole-4,5-dicarboxyl­ate ligands. The other Co(II) ion is bonded to four O atoms and two N atoms from four imidazole-4,5-dicarboxyl­ate ligands. These metal coordination units are connected by bridging imidazole-4,5-dicarboxyl­ate ligands, generating a three-dimensional network. The crystal structure is further stabilized by N—H⋯O, O—H⋯O, and C—H⋯O hydrogen-bonding inter­actions between the water mol­ecules and the imidazole-4,5-dicarboxyl­ate ligands. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238609/ /pubmed/22199500 http://dx.doi.org/10.1107/S1600536811045764 Text en © Li-Cai Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Li-Cai
Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title_full Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title_fullStr Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title_full_unstemmed Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title_short Poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(II)dilutetium(III)] dihydrate]
title_sort poly[[tetra­aqua­bis­(μ(3)-imidazole-4,5-dicarboxyl­ato)tetra­kis­(μ(2)-imidazole-4,5-dicarboxyl­ato)tricobalt(ii)dilutetium(iii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238609/
https://www.ncbi.nlm.nih.gov/pubmed/22199500
http://dx.doi.org/10.1107/S1600536811045764
work_keys_str_mv AT zhulicai polytetraaquabism3imidazole45dicarboxylatotetrakism2imidazole45dicarboxylatotricobaltiidilutetiumiiidihydrate