Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]

In the title compound, [Yb(2)(C(5)H(2)N(2)O(4))(2)(SO(4))(H(2)O)(2)](n), the Yb(III) ion is eight-coordinated by four O atoms and one N atom from three imidazole-4,5-dicarboxyl­ate ligands, two O atoms from one SO(4) (2−) anion (site symmetry 2), as well as one O atom of a water mol­ecule, giving a...

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Detalles Bibliográficos
Autor principal: Zhu, Li-Cai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238610/
https://www.ncbi.nlm.nih.gov/pubmed/22199501
http://dx.doi.org/10.1107/S1600536811045673
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author Zhu, Li-Cai
author_facet Zhu, Li-Cai
author_sort Zhu, Li-Cai
collection PubMed
description In the title compound, [Yb(2)(C(5)H(2)N(2)O(4))(2)(SO(4))(H(2)O)(2)](n), the Yb(III) ion is eight-coordinated by four O atoms and one N atom from three imidazole-4,5-dicarboxyl­ate ligands, two O atoms from one SO(4) (2−) anion (site symmetry 2), as well as one O atom of a water mol­ecule, giving a bicapped trigonal–prismatic coordination geometry. The metal coordination units are connected by bridging imidazole-4,5-dicarboxyl­ate and sulfate ligands, generating a heterometallic layer. The layers are stacked along the a axis via N—H⋯O, O—H⋯O, and C—H⋯O hydrogen-bonding inter­actions, generating a three-dimensional framework.
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spelling pubmed-32386102011-12-23 Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Yb(2)(C(5)H(2)N(2)O(4))(2)(SO(4))(H(2)O)(2)](n), the Yb(III) ion is eight-coordinated by four O atoms and one N atom from three imidazole-4,5-dicarboxyl­ate ligands, two O atoms from one SO(4) (2−) anion (site symmetry 2), as well as one O atom of a water mol­ecule, giving a bicapped trigonal–prismatic coordination geometry. The metal coordination units are connected by bridging imidazole-4,5-dicarboxyl­ate and sulfate ligands, generating a heterometallic layer. The layers are stacked along the a axis via N—H⋯O, O—H⋯O, and C—H⋯O hydrogen-bonding inter­actions, generating a three-dimensional framework. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238610/ /pubmed/22199501 http://dx.doi.org/10.1107/S1600536811045673 Text en © Li-Cai Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Li-Cai
Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title_full Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title_fullStr Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title_full_unstemmed Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title_short Poly[diaqua­bis­(μ(3)-1H-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(III)]
title_sort poly[diaqua­bis­(μ(3)-1h-imidazole-4,5-dicarboxyl­ato)(μ(2)-sulfato)­diytterbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238610/
https://www.ncbi.nlm.nih.gov/pubmed/22199501
http://dx.doi.org/10.1107/S1600536811045673
work_keys_str_mv AT zhulicai polydiaquabism31himidazole45dicarboxylatom2sulfatodiytterbiumiii

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