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Tetraaquabis(2-methyl-1H-imidazole-κN (3))cobalt(II) naphthalene-1,5-disulfonate
In the title complex, [Co(C(4)H(6)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co(II) ion is coordinated by four water molecules and two 2-methy...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238612/ https://www.ncbi.nlm.nih.gov/pubmed/22199503 http://dx.doi.org/10.1107/S160053681104548X |
| _version_ | 1782219021637124096 |
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| author | Jin, Yu |
| author_facet | Jin, Yu |
| author_sort | Jin, Yu |
| collection | PubMed |
| description | In the title complex, [Co(C(4)H(6)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co(II) ion is coordinated by four water molecules and two 2-methylimidazole ligands, resulting in a trans-octahedral coordination geometry. The existence of strong N—H⋯O and O—H⋯O hydrogen-bonding interactions gives rise to a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-3238612 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386122011-12-23 Tetraaquabis(2-methyl-1H-imidazole-κN (3))cobalt(II) naphthalene-1,5-disulfonate Jin, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(4)H(6)N(2))(2)(H(2)O)(4)](C(10)H(6)O(6)S(2)), the cation and anion both reside on crystallographic inversion centers, such that the asymmetric unit comprises one half cation and one half anion. The central Co(II) ion is coordinated by four water molecules and two 2-methylimidazole ligands, resulting in a trans-octahedral coordination geometry. The existence of strong N—H⋯O and O—H⋯O hydrogen-bonding interactions gives rise to a three-dimensional structure. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238612/ /pubmed/22199503 http://dx.doi.org/10.1107/S160053681104548X Text en © Yu Jin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Jin, Yu Tetraaquabis(2-methyl-1H-imidazole-κN (3))cobalt(II) naphthalene-1,5-disulfonate |
| title | Tetraaquabis(2-methyl-1H-imidazole-κN
(3))cobalt(II) naphthalene-1,5-disulfonate |
| title_full | Tetraaquabis(2-methyl-1H-imidazole-κN
(3))cobalt(II) naphthalene-1,5-disulfonate |
| title_fullStr | Tetraaquabis(2-methyl-1H-imidazole-κN
(3))cobalt(II) naphthalene-1,5-disulfonate |
| title_full_unstemmed | Tetraaquabis(2-methyl-1H-imidazole-κN
(3))cobalt(II) naphthalene-1,5-disulfonate |
| title_short | Tetraaquabis(2-methyl-1H-imidazole-κN
(3))cobalt(II) naphthalene-1,5-disulfonate |
| title_sort | tetraaquabis(2-methyl-1h-imidazole-κn
(3))cobalt(ii) naphthalene-1,5-disulfonate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238612/ https://www.ncbi.nlm.nih.gov/pubmed/22199503 http://dx.doi.org/10.1107/S160053681104548X |
| work_keys_str_mv | AT jinyu tetraaquabis2methyl1himidazolekn3cobaltiinaphthalene15disulfonate |