Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate

The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3−) anions, Cl(−) anions and uncoordinated water mol­ecules. The Bi(III) cation is coordinated by six Cl(−) anions in a slightly distorted octa­hedral geometry. The diprot...

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Detalles Bibliográficos
Autores principales: Gao, Yu-Hua, Liu, Xiao-Jia, Sun, Lei, Le, Wen-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238614/
https://www.ncbi.nlm.nih.gov/pubmed/22199505
http://dx.doi.org/10.1107/S1600536811045594
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author Gao, Yu-Hua
Liu, Xiao-Jia
Sun, Lei
Le, Wen-Jun
author_facet Gao, Yu-Hua
Liu, Xiao-Jia
Sun, Lei
Le, Wen-Jun
author_sort Gao, Yu-Hua
collection PubMed
description The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3−) anions, Cl(−) anions and uncoordinated water mol­ecules. The Bi(III) cation is coordinated by six Cl(−) anions in a slightly distorted octa­hedral geometry. The diprotonated piperazine ring adopts a chair conformation. In the crystal, extensive inter­molecular N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds occur.
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spelling pubmed-32386142011-12-23 Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate Gao, Yu-Hua Liu, Xiao-Jia Sun, Lei Le, Wen-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3−) anions, Cl(−) anions and uncoordinated water mol­ecules. The Bi(III) cation is coordinated by six Cl(−) anions in a slightly distorted octa­hedral geometry. The diprotonated piperazine ring adopts a chair conformation. In the crystal, extensive inter­molecular N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds occur. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238614/ /pubmed/22199505 http://dx.doi.org/10.1107/S1600536811045594 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Yu-Hua
Liu, Xiao-Jia
Sun, Lei
Le, Wen-Jun
Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title_full Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title_fullStr Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title_full_unstemmed Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title_short Bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(III) chloride monohydrate
title_sort bis(piperazine-1,4-diium) hexa­chlorido­bismuthate(iii) chloride monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238614/
https://www.ncbi.nlm.nih.gov/pubmed/22199505
http://dx.doi.org/10.1107/S1600536811045594
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AT sunlei bispiperazine14diiumhexachloridobismuthateiiichloridemonohydrate
AT lewenjun bispiperazine14diiumhexachloridobismuthateiiichloridemonohydrate

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