Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium

In the title compound, [Cd(C(11)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) cation is located on an inversion center and is coordinated by four N atoms from two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazol­ide anions and two water mol­ecules in a distorted octa­hedral geometry. The triazolide ligand is n...

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Detalles Bibliográficos
Autores principales: Yang, Jing-Jing, Zhao, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238616/
https://www.ncbi.nlm.nih.gov/pubmed/22199507
http://dx.doi.org/10.1107/S1600536811045545
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author Yang, Jing-Jing
Zhao, Jun
author_facet Yang, Jing-Jing
Zhao, Jun
author_sort Yang, Jing-Jing
collection PubMed
description In the title compound, [Cd(C(11)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) cation is located on an inversion center and is coordinated by four N atoms from two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazol­ide anions and two water mol­ecules in a distorted octa­hedral geometry. The triazolide ligand is nearly planar: the central triazole ring is oriented at dihedral angles of 4.63 (13) and 8.41 (13)° with respect to the pyrazine and pyridine rings. Inter­molecular O—H⋯N hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular network parallel to (001).
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spelling pubmed-32386162011-12-23 Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium Yang, Jing-Jing Zhao, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(11)H(7)N(6))(2)(H(2)O)(2)], the Cd(II) cation is located on an inversion center and is coordinated by four N atoms from two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazol­ide anions and two water mol­ecules in a distorted octa­hedral geometry. The triazolide ligand is nearly planar: the central triazole ring is oriented at dihedral angles of 4.63 (13) and 8.41 (13)° with respect to the pyrazine and pyridine rings. Inter­molecular O—H⋯N hydrogen bonds link the mol­ecules into a two-dimensional supra­molecular network parallel to (001). International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238616/ /pubmed/22199507 http://dx.doi.org/10.1107/S1600536811045545 Text en © Yang and Zhao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Jing-Jing
Zhao, Jun
Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title_full Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title_fullStr Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title_full_unstemmed Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title_short Diaqua­bis­[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]cadmium
title_sort diaqua­bis­[5-(pyrazin-2-yl-κn (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κn (1)]cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238616/
https://www.ncbi.nlm.nih.gov/pubmed/22199507
http://dx.doi.org/10.1107/S1600536811045545
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