[η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)

In the title compound, [Ti(C(8)H(13)Si)(C(11)H(21)Si(2))Cl(2)], the Ti(IV) atom is bonded to two Cl atoms, one 1,3-bis­(trimethyl­sil­yl)cyclo­penta­dienyl (Si(2)Cp) and one (trimethyl­sil­yl)cyclo­penta­dienyl ring (SiCp). The Si(2)Cp centroid–titanium distance is 2.0763 (10) Å and the SiCp centroi...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238619/
https://www.ncbi.nlm.nih.gov/pubmed/22199510
http://dx.doi.org/10.1107/S1600536811046228
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author Perdih, Franc
author_facet Perdih, Franc
author_sort Perdih, Franc
collection PubMed
description In the title compound, [Ti(C(8)H(13)Si)(C(11)H(21)Si(2))Cl(2)], the Ti(IV) atom is bonded to two Cl atoms, one 1,3-bis­(trimethyl­sil­yl)cyclo­penta­dienyl (Si(2)Cp) and one (trimethyl­sil­yl)cyclo­penta­dienyl ring (SiCp). The Si(2)Cp centroid–titanium distance is 2.0763 (10) Å and the SiCp centroid–titanium distance is 2.0793 (10) Å. The angle subtended at the Ti atom by the centroids of both cyclo­penta­dienyl rings is 131.22 (4)° and the Cl—Ti—Cl angle is 94.14 (2)°.
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spelling pubmed-32386192011-12-23 [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV) Perdih, Franc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ti(C(8)H(13)Si)(C(11)H(21)Si(2))Cl(2)], the Ti(IV) atom is bonded to two Cl atoms, one 1,3-bis­(trimethyl­sil­yl)cyclo­penta­dienyl (Si(2)Cp) and one (trimethyl­sil­yl)cyclo­penta­dienyl ring (SiCp). The Si(2)Cp centroid–titanium distance is 2.0763 (10) Å and the SiCp centroid–titanium distance is 2.0793 (10) Å. The angle subtended at the Ti atom by the centroids of both cyclo­penta­dienyl rings is 131.22 (4)° and the Cl—Ti—Cl angle is 94.14 (2)°. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238619/ /pubmed/22199510 http://dx.doi.org/10.1107/S1600536811046228 Text en © Franc Perdih 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Perdih, Franc
[η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title_full [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title_fullStr [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title_full_unstemmed [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title_short [η(5)-1,3-Bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(IV)
title_sort [η(5)-1,3-bis(trimethyl­sil­yl)cyclo­penta­dien­yl]dichlorido[η(5)-(trimethyl­sil­yl)cyclo­penta­dien­yl]titanium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238619/
https://www.ncbi.nlm.nih.gov/pubmed/22199510
http://dx.doi.org/10.1107/S1600536811046228
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