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Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)

The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-mol­ecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1...

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Detalles Bibliográficos
Autores principales: Tsaryk, Natalia V., Dudko, Anatolij V., Kozachkova, Alexandra N., Pekhnyo, Vasily I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238620/
https://www.ncbi.nlm.nih.gov/pubmed/22199511
http://dx.doi.org/10.1107/S1600536811045120
Descripción
Sumario:The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-mol­ecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-bis­phospho­nato ligands in the equatorial plane and two water mol­ecules located in axial positions. The ligand mol­ecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure.