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Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)

The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-mol­ecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1...

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Autores principales: Tsaryk, Natalia V., Dudko, Anatolij V., Kozachkova, Alexandra N., Pekhnyo, Vasily I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238620/
https://www.ncbi.nlm.nih.gov/pubmed/22199511
http://dx.doi.org/10.1107/S1600536811045120
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author Tsaryk, Natalia V.
Dudko, Anatolij V.
Kozachkova, Alexandra N.
Pekhnyo, Vasily I.
author_facet Tsaryk, Natalia V.
Dudko, Anatolij V.
Kozachkova, Alexandra N.
Pekhnyo, Vasily I.
author_sort Tsaryk, Natalia V.
collection PubMed
description The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-mol­ecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-bis­phospho­nato ligands in the equatorial plane and two water mol­ecules located in axial positions. The ligand mol­ecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure.
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spelling pubmed-32386202011-12-23 Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II) Tsaryk, Natalia V. Dudko, Anatolij V. Kozachkova, Alexandra N. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-mol­ecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octa­hedral coordination geometry defined by four O atoms of two 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-bis­phospho­nato ligands in the equatorial plane and two water mol­ecules located in axial positions. The ligand mol­ecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, mol­ecules are inter­linked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238620/ /pubmed/22199511 http://dx.doi.org/10.1107/S1600536811045120 Text en © Tsaryk et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tsaryk, Natalia V.
Dudko, Anatolij V.
Kozachkova, Alexandra N.
Pekhnyo, Vasily I.
Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title_full Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title_fullStr Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title_full_unstemmed Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title_short Diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) O,O′)cobalt(II)
title_sort diaqua­bis­(dihydrogen 3-aza­niumyl-1-hy­droxy­propyl­idene-1,1-di­phos­phon­ato-κ(2) o,o′)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238620/
https://www.ncbi.nlm.nih.gov/pubmed/22199511
http://dx.doi.org/10.1107/S1600536811045120
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