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Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2) O,O′)cobalt(II)
The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-molecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octahedral coordination geometry defined by four O atoms of two 3-azaniumyl-1-hydroxypropylidene-1...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238620/ https://www.ncbi.nlm.nih.gov/pubmed/22199511 http://dx.doi.org/10.1107/S1600536811045120 |
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author | Tsaryk, Natalia V. Dudko, Anatolij V. Kozachkova, Alexandra N. Pekhnyo, Vasily I. |
author_facet | Tsaryk, Natalia V. Dudko, Anatolij V. Kozachkova, Alexandra N. Pekhnyo, Vasily I. |
author_sort | Tsaryk, Natalia V. |
collection | PubMed |
description | The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-molecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octahedral coordination geometry defined by four O atoms of two 3-azaniumyl-1-hydroxypropylidene-1,1-bisphosphonato ligands in the equatorial plane and two water molecules located in axial positions. The ligand molecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, molecules are interlinked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure. |
format | Online Article Text |
id | pubmed-3238620 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386202011-12-23 Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2) O,O′)cobalt(II) Tsaryk, Natalia V. Dudko, Anatolij V. Kozachkova, Alexandra N. Pekhnyo, Vasily I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of title compound, [Co(C(3)H(10)NO(7)P(2))(2)(H(2)O)(2)], contains one half-molecule of the complex. The Co(II) atom is located on an inversion centre and displays a distorted octahedral coordination geometry defined by four O atoms of two 3-azaniumyl-1-hydroxypropylidene-1,1-bisphosphonato ligands in the equatorial plane and two water molecules located in axial positions. The ligand molecules, which exist in a zwitterionic state, form two six-membered chelate rings with chair conformations. In the crystal, molecules are interlinked by O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238620/ /pubmed/22199511 http://dx.doi.org/10.1107/S1600536811045120 Text en © Tsaryk et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tsaryk, Natalia V. Dudko, Anatolij V. Kozachkova, Alexandra N. Pekhnyo, Vasily I. Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2) O,O′)cobalt(II) |
title | Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
O,O′)cobalt(II) |
title_full | Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
O,O′)cobalt(II) |
title_fullStr | Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
O,O′)cobalt(II) |
title_full_unstemmed | Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
O,O′)cobalt(II) |
title_short | Diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
O,O′)cobalt(II) |
title_sort | diaquabis(dihydrogen 3-azaniumyl-1-hydroxypropylidene-1,1-diphosphonato-κ(2)
o,o′)cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238620/ https://www.ncbi.nlm.nih.gov/pubmed/22199511 http://dx.doi.org/10.1107/S1600536811045120 |
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