trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)

The title complex, [RhCl(C(21)H(21)O(3)P)(2)(CO)], is a rhodium analogue to Vaska’s complex with para-meth­oxy substituents on the six phosphan­yl–aryl units. Two independent mol­ecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the chloride...

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Detalles Bibliográficos
Autores principales: Warsink, Stefan, Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238621/
https://www.ncbi.nlm.nih.gov/pubmed/22199512
http://dx.doi.org/10.1107/S1600536811046150
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author Warsink, Stefan
Roodt, Andreas
author_facet Warsink, Stefan
Roodt, Andreas
author_sort Warsink, Stefan
collection PubMed
description The title complex, [RhCl(C(21)H(21)O(3)P)(2)(CO)], is a rhodium analogue to Vaska’s complex with para-meth­oxy substituents on the six phosphan­yl–aryl units. Two independent mol­ecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the chloride and carbonyl ligands to exhibit a positional disorder in a 0.5:0.5 ratio. The two Rh(I) atoms exhibit a distorted square-planar geometry. There are a few weak intra­molecular C—H⋯X inter­actions (X = O, Cl). Inter­estingly, no significant inter­molecular inter­actions are found between the two independent mol­ecules.
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spelling pubmed-32386212011-12-23 trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I) Warsink, Stefan Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [RhCl(C(21)H(21)O(3)P)(2)(CO)], is a rhodium analogue to Vaska’s complex with para-meth­oxy substituents on the six phosphan­yl–aryl units. Two independent mol­ecules are present in the unit cell, with their metal atoms both located on an inversion centre. This causes the chloride and carbonyl ligands to exhibit a positional disorder in a 0.5:0.5 ratio. The two Rh(I) atoms exhibit a distorted square-planar geometry. There are a few weak intra­molecular C—H⋯X inter­actions (X = O, Cl). Inter­estingly, no significant inter­molecular inter­actions are found between the two independent mol­ecules. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238621/ /pubmed/22199512 http://dx.doi.org/10.1107/S1600536811046150 Text en © Warsink and Roodt 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Warsink, Stefan
Roodt, Andreas
trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title_full trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title_fullStr trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title_full_unstemmed trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title_short trans-Carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κP]rhodium(I)
title_sort trans-carbonyl­chloridobis[tris­(4-meth­oxy­phen­yl)phosphane-κp]rhodium(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238621/
https://www.ncbi.nlm.nih.gov/pubmed/22199512
http://dx.doi.org/10.1107/S1600536811046150
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