Bis(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II)

In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl­acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa­hedral environment, with Co...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238622/
https://www.ncbi.nlm.nih.gov/pubmed/22199513
http://dx.doi.org/10.1107/S1600536811046216
Descripción
Sumario:In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl­acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa­hedral environment, with Co—O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co—N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π–π inter­actions.

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