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Bis(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II)
In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238622/ https://www.ncbi.nlm.nih.gov/pubmed/22199513 http://dx.doi.org/10.1107/S1600536811046216 |
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| author | Perdih, Franc |
| author_facet | Perdih, Franc |
| author_sort | Perdih, Franc |
| collection | PubMed |
| description | In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co—O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co—N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π–π interactions. |
| format | Online Article Text |
| id | pubmed-3238622 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386222011-12-23 Bis(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) Perdih, Franc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetylacetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octahedral environment, with Co—O bond lengths of 2.0565 (11) and 2.0641 (11) Å and Co—N bond lengths of 2.1630 (12) Å. In the crystal, there are no significant hydrogen-bonding or π–π interactions. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238622/ /pubmed/22199513 http://dx.doi.org/10.1107/S1600536811046216 Text en © Franc Perdih 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Perdih, Franc Bis(pentane-2,4-dionato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cobalt(II) |
| title | Bis(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
| title_full | Bis(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
| title_fullStr | Bis(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
| title_full_unstemmed | Bis(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
| title_short | Bis(pentane-2,4-dionato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cobalt(II) |
| title_sort | bis(pentane-2,4-dionato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238622/ https://www.ncbi.nlm.nih.gov/pubmed/22199513 http://dx.doi.org/10.1107/S1600536811046216 |
| work_keys_str_mv | AT perdihfranc bispentane24dionatok2oo110phenanthrolinek2nncobaltii |