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Bis(1H-benzotriazole-4-sulfonato-κ(2) N (3),O)(2,2′-bipyridyl-κ(2) N,N′)cadmium
In the title complex, [Cd(C(6)H(4)N(3)O(3)S)(2)(C(10)H(8)N(2))], the Cd(2+) cation is located on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related benzotriazole-4-sulfonate anions and two N atoms from a 2,2-bipyridyl ligand, displaying a distorted CdN(4)O(...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238624/ https://www.ncbi.nlm.nih.gov/pubmed/22199515 http://dx.doi.org/10.1107/S160053681104596X |
| _version_ | 1782219024409559040 |
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| author | Zhu, Xiao-Hong Cheng, Xiao-Chun |
| author_facet | Zhu, Xiao-Hong Cheng, Xiao-Chun |
| author_sort | Zhu, Xiao-Hong |
| collection | PubMed |
| description | In the title complex, [Cd(C(6)H(4)N(3)O(3)S)(2)(C(10)H(8)N(2))], the Cd(2+) cation is located on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related benzotriazole-4-sulfonate anions and two N atoms from a 2,2-bipyridyl ligand, displaying a distorted CdN(4)O(2) octahedral geometry. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding interactions. |
| format | Online Article Text |
| id | pubmed-3238624 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386242011-12-23 Bis(1H-benzotriazole-4-sulfonato-κ(2) N (3),O)(2,2′-bipyridyl-κ(2) N,N′)cadmium Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(6)H(4)N(3)O(3)S)(2)(C(10)H(8)N(2))], the Cd(2+) cation is located on a twofold rotation axis and is coordinated by two N and two O atoms from two symmetry-related benzotriazole-4-sulfonate anions and two N atoms from a 2,2-bipyridyl ligand, displaying a distorted CdN(4)O(2) octahedral geometry. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238624/ /pubmed/22199515 http://dx.doi.org/10.1107/S160053681104596X Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Xiao-Hong Cheng, Xiao-Chun Bis(1H-benzotriazole-4-sulfonato-κ(2) N (3),O)(2,2′-bipyridyl-κ(2) N,N′)cadmium |
| title | Bis(1H-benzotriazole-4-sulfonato-κ(2)
N
(3),O)(2,2′-bipyridyl-κ(2)
N,N′)cadmium |
| title_full | Bis(1H-benzotriazole-4-sulfonato-κ(2)
N
(3),O)(2,2′-bipyridyl-κ(2)
N,N′)cadmium |
| title_fullStr | Bis(1H-benzotriazole-4-sulfonato-κ(2)
N
(3),O)(2,2′-bipyridyl-κ(2)
N,N′)cadmium |
| title_full_unstemmed | Bis(1H-benzotriazole-4-sulfonato-κ(2)
N
(3),O)(2,2′-bipyridyl-κ(2)
N,N′)cadmium |
| title_short | Bis(1H-benzotriazole-4-sulfonato-κ(2)
N
(3),O)(2,2′-bipyridyl-κ(2)
N,N′)cadmium |
| title_sort | bis(1h-benzotriazole-4-sulfonato-κ(2)
n
(3),o)(2,2′-bipyridyl-κ(2)
n,n′)cadmium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238624/ https://www.ncbi.nlm.nih.gov/pubmed/22199515 http://dx.doi.org/10.1107/S160053681104596X |
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