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Tetraaquabis[1-(3-carboxyphenyl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis(4,5-carboxybenzene-1,2-dicarboxylate) 2.5-hydrate
In the complex cation of the title compound, [Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)](C(10)H(4)O(8))(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carboxyphenyl)-4,4′-bipyridin-1-ium ligands and four water molecules in a distorted octahedra...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238626/ https://www.ncbi.nlm.nih.gov/pubmed/22199517 http://dx.doi.org/10.1107/S1600536811045156 |
Sumario: | In the complex cation of the title compound, [Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)](C(10)H(4)O(8))(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carboxyphenyl)-4,4′-bipyridin-1-ium ligands and four water molecules in a distorted octahedral geometry. The pyromellitate anion is double deprotonated. O—H⋯O and C—H⋯O hydrogen bonds connect the cations, anions and uncoordinated water molecules into a three-dimensional supramolecular network. One of the two lattice water molecules shows an occupancy of 0.25. An intramolecular O—H⋯O hydrogen bond is present in the anion. |
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