Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate

In the complex cation of the title compound, [Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)](C(10)H(4)O(8))(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium ligands and four water mol­ecules in a distorted octa­hedra...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Jie, Tan, Yi, Fu, Zhiyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238626/
https://www.ncbi.nlm.nih.gov/pubmed/22199517
http://dx.doi.org/10.1107/S1600536811045156
_version_ 1782219024869883904
author Zhang, Jie
Tan, Yi
Fu, Zhiyong
author_facet Zhang, Jie
Tan, Yi
Fu, Zhiyong
author_sort Zhang, Jie
collection PubMed
description In the complex cation of the title compound, [Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)](C(10)H(4)O(8))(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium ligands and four water mol­ecules in a distorted octa­hedral geometry. The pyromellitate anion is double deprotonated. O—H⋯O and C—H⋯O hydrogen bonds connect the cations, anions and uncoordinated water mol­ecules into a three-dimensional supra­molecular network. One of the two lattice water molecules shows an occupancy of 0.25. An intra­molecular O—H⋯O hydrogen bond is present in the anion.
format Online
Article
Text
id pubmed-3238626
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386262011-12-23 Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate Zhang, Jie Tan, Yi Fu, Zhiyong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the complex cation of the title compound, [Zn(C(17)H(13)N(2)O(2))(2)(H(2)O)(4)](C(10)H(4)O(8))(2)·2.5H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium ligands and four water mol­ecules in a distorted octa­hedral geometry. The pyromellitate anion is double deprotonated. O—H⋯O and C—H⋯O hydrogen bonds connect the cations, anions and uncoordinated water mol­ecules into a three-dimensional supra­molecular network. One of the two lattice water molecules shows an occupancy of 0.25. An intra­molecular O—H⋯O hydrogen bond is present in the anion. International Union of Crystallography 2011-11-05 /pmc/articles/PMC3238626/ /pubmed/22199517 http://dx.doi.org/10.1107/S1600536811045156 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jie
Tan, Yi
Fu, Zhiyong
Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title_full Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title_fullStr Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title_full_unstemmed Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title_short Tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κN (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
title_sort tetra­aqua­bis­[1-(3-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium-κn (1′)]zinc bis­(4,5-carb­oxy­benzene-1,2-dicarboxyl­ate) 2.5-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238626/
https://www.ncbi.nlm.nih.gov/pubmed/22199517
http://dx.doi.org/10.1107/S1600536811045156
work_keys_str_mv AT zhangjie tetraaquabis13carboxyphenyl44bipyridin1iumkn1zincbis45carboxybenzene12dicarboxylate25hydrate
AT tanyi tetraaquabis13carboxyphenyl44bipyridin1iumkn1zincbis45carboxybenzene12dicarboxylate25hydrate
AT fuzhiyong tetraaquabis13carboxyphenyl44bipyridin1iumkn1zincbis45carboxybenzene12dicarboxylate25hydrate

Ejemplares similares