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Di-μ-azido-κ(4) N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate
In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octahedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symm...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238627/ https://www.ncbi.nlm.nih.gov/pubmed/22199518 http://dx.doi.org/10.1107/S1600536811045909 |
Sumario: | In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octahedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symmetry-related azide ligands bridge in μ(2)-modes giving a Cu⋯Cu distance of 3.533 (2) Å. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. In addition, there are weak intermolecular C—H⋯N hydrogen bonds and π–π stacking interactions with centroid–centroid distances ranging from 3.562 (2) to 3.974 (2) Å. |
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