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Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate

In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octa­hedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symm...

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Autor principal: Luo, Yuan-yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238627/
https://www.ncbi.nlm.nih.gov/pubmed/22199518
http://dx.doi.org/10.1107/S1600536811045909
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author Luo, Yuan-yuan
author_facet Luo, Yuan-yuan
author_sort Luo, Yuan-yuan
collection PubMed
description In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octa­hedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symmetry-related azide ligands bridge in μ(2)-modes giving a Cu⋯Cu distance of 3.533 (2) Å. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. In addition, there are weak inter­molecular C—H⋯N hydrogen bonds and π–π stacking inter­actions with centroid–centroid distances ranging from 3.562 (2) to 3.974 (2) Å.
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spelling pubmed-32386272011-12-23 Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate Luo, Yuan-yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octa­hedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symmetry-related azide ligands bridge in μ(2)-modes giving a Cu⋯Cu distance of 3.533 (2) Å. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. In addition, there are weak inter­molecular C—H⋯N hydrogen bonds and π–π stacking inter­actions with centroid–centroid distances ranging from 3.562 (2) to 3.974 (2) Å. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238627/ /pubmed/22199518 http://dx.doi.org/10.1107/S1600536811045909 Text en © Yuan-yuan Luo 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Luo, Yuan-yuan
Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title_full Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title_fullStr Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title_full_unstemmed Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title_short Di-μ-azido-κ(4) N:N-bis­{aqua­[bis­(1H-benzimidazol-2-ylmeth­yl)amine]­copper(II)} dinitrate
title_sort di-μ-azido-κ(4) n:n-bis­{aqua­[bis­(1h-benzimidazol-2-ylmeth­yl)amine]­copper(ii)} dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238627/
https://www.ncbi.nlm.nih.gov/pubmed/22199518
http://dx.doi.org/10.1107/S1600536811045909
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