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Di-μ-azido-κ(4) N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate
In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octahedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symm...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238627/ https://www.ncbi.nlm.nih.gov/pubmed/22199518 http://dx.doi.org/10.1107/S1600536811045909 |
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author | Luo, Yuan-yuan |
author_facet | Luo, Yuan-yuan |
author_sort | Luo, Yuan-yuan |
collection | PubMed |
description | In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octahedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symmetry-related azide ligands bridge in μ(2)-modes giving a Cu⋯Cu distance of 3.533 (2) Å. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. In addition, there are weak intermolecular C—H⋯N hydrogen bonds and π–π stacking interactions with centroid–centroid distances ranging from 3.562 (2) to 3.974 (2) Å. |
format | Online Article Text |
id | pubmed-3238627 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386272011-12-23 Di-μ-azido-κ(4) N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate Luo, Yuan-yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(N(3))(2)(C(16)H(15)N(5))(2)(H(2)O)(2)](NO(3))(2), the Cu(II) ion is in a distorted octahedral coordination environment with long axial Cu—N(azide) [2.821 (6) Å] and Cu—O(water) [2.747 (5) Å] bonds as a result of the Jahn–Teller effect. Two symmetry-related azide ligands bridge in μ(2)-modes giving a Cu⋯Cu distance of 3.533 (2) Å. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. In addition, there are weak intermolecular C—H⋯N hydrogen bonds and π–π stacking interactions with centroid–centroid distances ranging from 3.562 (2) to 3.974 (2) Å. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238627/ /pubmed/22199518 http://dx.doi.org/10.1107/S1600536811045909 Text en © Yuan-yuan Luo 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Luo, Yuan-yuan Di-μ-azido-κ(4) N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title | Di-μ-azido-κ(4)
N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title_full | Di-μ-azido-κ(4)
N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title_fullStr | Di-μ-azido-κ(4)
N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title_full_unstemmed | Di-μ-azido-κ(4)
N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title_short | Di-μ-azido-κ(4)
N:N-bis{aqua[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II)} dinitrate |
title_sort | di-μ-azido-κ(4)
n:n-bis{aqua[bis(1h-benzimidazol-2-ylmethyl)amine]copper(ii)} dinitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238627/ https://www.ncbi.nlm.nih.gov/pubmed/22199518 http://dx.doi.org/10.1107/S1600536811045909 |
work_keys_str_mv | AT luoyuanyuan dimazidok4nnbisaquabis1hbenzimidazol2ylmethylaminecopperiidinitrate |