catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa­hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro­benzoate ligands, two O atoms from methanol ligands, and...

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Detalles Bibliográficos
Autores principales: Hyun, Min Young, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238628/
https://www.ncbi.nlm.nih.gov/pubmed/22199519
http://dx.doi.org/10.1107/S1600536811046149
Descripción
Sumario:In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa­hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro­benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the Co(II) ions, forming chains extending along [010]. An intra­chain O—H⋯O hydrogen bond is observed.

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