catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]

In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa­hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro­benzoate ligands, two O atoms from methanol ligands, and...

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Detalles Bibliográficos
Autores principales: Hyun, Min Young, Kim, Pan-Gi, Kim, Cheal, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238628/
https://www.ncbi.nlm.nih.gov/pubmed/22199519
http://dx.doi.org/10.1107/S1600536811046149
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author Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_facet Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
author_sort Hyun, Min Young
collection PubMed
description In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa­hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro­benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the Co(II) ions, forming chains extending along [010]. An intra­chain O—H⋯O hydrogen bond is observed.
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spelling pubmed-32386282011-12-23 catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] Hyun, Min Young Kim, Pan-Gi Kim, Cheal Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(3)Cl(2)O(2))(2)(C(10)H(8)N(2))(CH(3)OH)(2)](n), the Co(II) ion lies on a twofold rotation axis and is in a slightly distorted octa­hedral CdO(4)N(2) environment, formed by two O atoms from monodentate dichloro­benzoate ligands, two O atoms from methanol ligands, and two N atoms from trans-related 4,4′-bipyridine ligands. The bipyridine ligands also lies on a twofold rotation axis and bridge the Co(II) ions, forming chains extending along [010]. An intra­chain O—H⋯O hydrogen bond is observed. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238628/ /pubmed/22199519 http://dx.doi.org/10.1107/S1600536811046149 Text en © Hyun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hyun, Min Young
Kim, Pan-Gi
Kim, Cheal
Kim, Youngmee
catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_fullStr catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_short catena-Poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κO)cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
title_sort catena-poly[[bis­(2,4-dichloro­benzoato)bis­(methanol-κo)cobalt(ii)]-μ-4,4′-bipyridine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238628/
https://www.ncbi.nlm.nih.gov/pubmed/22199519
http://dx.doi.org/10.1107/S1600536811046149
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