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catena-Poly[[[triaquacopper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxylato-κ(3) N,N′:O] monohydrate]
The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydrothermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxylate bridging ligand in a sligthly distorted octahedral en...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238631/ https://www.ncbi.nlm.nih.gov/pubmed/22199522 http://dx.doi.org/10.1107/S1600536811046423 |
Sumario: | The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydrothermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxylate bridging ligand in a sligthly distorted octahedral environment. The 2,2-bipyridine-3,3′-dicarboxylate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O—H⋯O hydrogen bonds involving the water solvent molecules, forming a three-dimensional framework. |
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