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catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]

The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxyl­ate bridging ligand in a sligthly distorted octa­hedral en...

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Detalles Bibliográficos
Autores principales: Wu, Qihui, Wang, Fuxiang, Jiang, Nanqing, Cao, Li, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238631/
https://www.ncbi.nlm.nih.gov/pubmed/22199522
http://dx.doi.org/10.1107/S1600536811046423
Descripción
Sumario:The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxyl­ate bridging ligand in a sligthly distorted octa­hedral environment. The 2,2-bipyridine-3,3′-dicarboxyl­ate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O—H⋯O hydrogen bonds involving the water solvent mol­ecules, forming a three-dimensional framework.