catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]

The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxyl­ate bridging ligand in a sligthly distorted octa­hedral en...

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Detalles Bibliográficos
Autores principales: Wu, Qihui, Wang, Fuxiang, Jiang, Nanqing, Cao, Li, Pan, Qinhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238631/
https://www.ncbi.nlm.nih.gov/pubmed/22199522
http://dx.doi.org/10.1107/S1600536811046423
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author Wu, Qihui
Wang, Fuxiang
Jiang, Nanqing
Cao, Li
Pan, Qinhe
author_facet Wu, Qihui
Wang, Fuxiang
Jiang, Nanqing
Cao, Li
Pan, Qinhe
author_sort Wu, Qihui
collection PubMed
description The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxyl­ate bridging ligand in a sligthly distorted octa­hedral environment. The 2,2-bipyridine-3,3′-dicarboxyl­ate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O—H⋯O hydrogen bonds involving the water solvent mol­ecules, forming a three-dimensional framework.
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spelling pubmed-32386312011-12-23 catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate] Wu, Qihui Wang, Fuxiang Jiang, Nanqing Cao, Li Pan, Qinhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Cu(C(12)H(6)N(2)O(4))(H(2)O)(3)]·H(2)O}(n), was synthesized under hydro­thermal conditions. The Cu(2+) ion is six-coordinated by three water O atoms, and two N atoms and one O atom of the 2,2′-bipyridine-3,3′-dicarboxyl­ate bridging ligand in a sligthly distorted octa­hedral environment. The 2,2-bipyridine-3,3′-dicarboxyl­ate bridges link the Cu(2+) ions into chains along the b-axis direction. These chains are further linked by O—H⋯O hydrogen bonds involving the water solvent mol­ecules, forming a three-dimensional framework. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238631/ /pubmed/22199522 http://dx.doi.org/10.1107/S1600536811046423 Text en © Wu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Qihui
Wang, Fuxiang
Jiang, Nanqing
Cao, Li
Pan, Qinhe
catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title_full catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title_fullStr catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title_full_unstemmed catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title_short catena-Poly[[[triaqua­copper(II)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) N,N′:O] monohydrate]
title_sort catena-poly[[[triaqua­copper(ii)]-μ-2,2′-bipyridine-3,3′-dicarboxyl­ato-κ(3) n,n′:o] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238631/
https://www.ncbi.nlm.nih.gov/pubmed/22199522
http://dx.doi.org/10.1107/S1600536811046423
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