Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate

In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa­hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0...

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Detalles Bibliográficos
Autores principales: Veith, Michael, Belot, Celine, Huch, Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238632/
https://www.ncbi.nlm.nih.gov/pubmed/22199523
http://dx.doi.org/10.1107/S160053681104623X
Descripción
Sumario:In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa­hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.

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